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1Author    H. Schmidbaur, G. BlaschkeRequires cookie*
 Title    Ein Ylidkomplex des Rutheniums mit drei-und viergliedrigen Metallocyclen An Ylide Complex of Ruthenium with Three-and Four-Membered Metallocycles  
 Abstract    A spirometallocyclic complex of ruthenium with (CH3)2P(CH2)2, (CH3)2PCH2 and two (CH3)3P ligands (formula 5) is synthesized from (CH3)2P(CH2)2Li and frans-[(CH3)3P]4RuCl2 in the molar ratio 2:1. Two equivalents of (CHs^P are liberated and the ionic complex frans-[(CH3)3P]4Ru[CH2P(CH3)3]Cl + Cl _ is formed as a by-product. The products were characterized by analytical and spectroscopic data. 
  Reference    Z. Naturforsch. 35b, 584—587 (1980); eingegangen am 11. November 1979 
  Published    1980 
  Keywords    Ylide Complexes, Ruthenium, Metallocycle 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0584.pdf 
 Identifier    ZNB-1980-35b-0584 
 Volume    35 
2Author    Michael Schneider, Martin Wenzel, Gerd SchachschneiderRequires cookie*
 Title    Enzym atische H ydroxylierung von R uthenocen und O sm ocen durch Leber-M ikrosom en Enzymatic Hydroxylation of Ruthenocen and Osmocene  
 Abstract    In buffer solution (pH 7,4) ruthenocene and osmocene are far more stable than ferrocene. The metallocenes ruthenocene and osmocene are metabolized by microsomes of mouse liver in the presence o f NADPH and 0 2. The Ä'if-values are similar for both metallocenes, the rate of metabolism is higher for osmocene that for ruthenocene. 
  Reference    Z. Naturforsch. 37c, 136 (1982); received August 201981 
  Published    1982 
  Keywords    Metallocenes, Radiodiagnostics, Osmium, Ruthenium, Hydroxylation 
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 TEI-XML for    default:Reihe_C/37/ZNC-1982-37c-0136_n.pdf 
 Identifier    ZNC-1982-37c-0136_n 
 Volume    37 
3Author    Helmut Behrens, Anton JungbauerRequires cookie*
 Title    Über die Reaktionen von ein-und zweikernigen, kationischen ?/ 5 -Cyelopentadienyl-carbonyl-Komplexeii des Eisens, Rutheniums und Osmiums mit flüssigem Ammoniak [1] On the Reactions of Mono-and Dinuclear, Cationic ^-Cyclopentadienyl Carbonyl Complexes of Iron, Ruthenium and Osmium with Liquid Ammonia [1]  
 Abstract    The covalent carbamoyl compounds 7?5.c5H5Ru(CO)(L)(CONH2) (L = CO, MeCN, MeNC, PPh3, PEt3) and ^-CsHsOsfCOMCONI^) are formed by the reactions of the cationic complexes [7?5.C5H5Ru(CO)2(L)]+ (L = CO, MeCN, MeNC, PPh3, PEt3) and [^ 5 -C5H5Os(CO)3]+ with liquid NH3 below 10 °C. In contrast, the reaction of [^ 5 -C5H5Ru(CO)2(r? 2 -C2H4)]PF6 with liquid NH3 yields the quarternary ammonium salt 
  Reference    Z. Naturforsch. 34b, 1477—1486 (1979); eingegangen am 3. August 1979 
  Published    1979 
  Keywords    ^-Cyclopentadienyl Carbamoyl Carbonyl Complexes, Iron, Ruthenium, Osmium 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-1477.pdf 
 Identifier    ZNB-1979-34b-1477 
 Volume    34 
4Author    S. Frenzen, Hk Müller-BuschbaumRequires cookie*
 Title    Uber das gemischte Alkali-Erdalkalimetall-Oxoruthenat NaSr3R u 0 6 The Mixed Alkaline Alkaline E arth O xoruthenate NaSr3R u 0 6  
 Abstract    Single crystals of NaSr3R u 0 6 have been prepared in closed silver tubes and investigated by X-ray techniques^ This compound crystallizes with trigonal (rhombohedral) symmetry, space group Ö3d-R 3 c , a = 9.6069(8), c = 11.513(2) A, Z = 6, and is isotypic to compounds of the Sr4P t 0 6 type. The crystal structure is discussed with respect to related compounds with partial replacement o f alkaline earth elem ents by sodium and copper. 
  Reference    Z. Naturforsch. 50b, 581 (1995); eingegangen am 4. Oktober 1994 
  Published    1995 
  Keywords    Sodium, Strontium, Ruthenium, Oxide, Crystal Structure 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-0581.pdf 
 Identifier    ZNB-1995-50b-0581 
 Volume    50 
5Author    S. Frenzen, Hk Müller-BuschbaumRequires cookie*
 Title    Uber einen 9L-Perowskit der Zusammensetzung Ba9Ru3? 2Mn5?8027 On a 9L-Perovskite of the Composition Ba9Ru3 2Mn5 80 27  
 Abstract    Single crystals of Ba9Ru3 2Mn5 80 27 have been prepared by flux techniques. X-ray four circle diffractometer measurements led to trigonal (rhombohedral) symmetry, space group D3d-R 3 m , a = 5.7043(5), c = 21.255(4) A , Z = 1. This phase is isotypic to B a R u 0 3. The crystal structure and the occupation of the M3O i2 triple octahedra by ruthenium and manga­ nese are discussed with respect to other oxides containing M30 12 groups in an ordered and disordered way. 
  Reference    Z. Naturforsch. 50b, 585 (1995); eingegangen am 10. Oktober 1994 
  Published    1995 
  Keywords    Barium, Ruthenium, M anganese, Oxide, Perovskite, Structure 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-0585.pdf 
 Identifier    ZNB-1995-50b-0585 
 Volume    50 
6Author    Ralf Keuper, Nikolaus RischRequires cookie*
 Title    Ruthenium(II)-Komplexe mit neuartigen 1,10-Phenanthrolinliganden Ruthenium (II) Complexes with New Kinds of 1.10-Phenanthrolin Ligands  
 Abstract    Different pathways to Ru-com plexes are described using the hitherto unknown S-type terpyridines 3 and the known U-type ligands 4. The resulting hexafluorophosphates 6 and 7 have been spectroscopically characterized by 'H NM R and IR data and also by mass spectro­ metry and cyclic voltammetry. 
  Reference    Z. Naturforsch. 50b, 1115—1120 (1995); eingegangen am 7. Februar 1995 
  Published    1995 
  Keywords    Terpyridines, Ruthenium, NM R Spectra, Cyclic Voltammetry 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-1115.pdf 
 Identifier    ZNB-1995-50b-1115 
 Volume    50 
7Author    Markus Prem, Kurt Polbom, Wolfgang BeckRequires cookie*
 Title    Metallkomplexe mit biologisch wichtigen Liganden, C IX [1]. Metallorganische Verbindungen von Platin(II), Ruthenium(II), Rhodium (III) und Iridium (III) mit Oxocarbonyl-N-geschützten a-Am inosäuren und L-Methionylglycinat Metal Complexes with Biologically Important Ligands, CIX [1]. Organometallic Compounds o f Platinum(II), Ruthenium(II), Rhodium(III), and Iridium(III) with Oxocarbonyl-N-protected a-Amino Acids and L-Methionylglycinate  
 Abstract    The reaction o f m -(P h 3P)2PtCl2 with BOC-N-glycine and FMOC-N-alanine gives the carboxylate coordinated complexes as-(Ph3P)2Pt(Cl)(0 2CCH2N HB0 C) (1) and cis-(Ph3P)2Pt(C l)(02C C (H)(M e)N H FM 0C (2). Chloride and proton abstraction from 1 affords the N,Ö-chelate complex (Ph3P)2 P t(0 2C CH2N B 0C) (3). From the chloro-bridged compounds [Cp*MCl2] 2 (M = Rh, Ir), [(/?-cymene)RuCl2] 2 and BOC-N-L-MetGlyOH (L) the compounds Cp*M (Clj2L (4, 5) and (/?-cymene)Ru(Cl)2L (6) with the mono-dentate dipeptide are obtained which in the presence o f NaOMe form Ö,N,S-bis(chelate) complexes 7 -9 . The X-ray dif­ fraction analysis of the iridium 0,N,S chelate complex 8 shows a five membered and a seven membered chelate ring. 
  Reference    Z. Naturforsch. 53b, 1501—1505 (1998); eingegangen am 20. Juli 1998 
  Published    1998 
  Keywords    Platinum, Ruthenium, Rhodium, Iridium Complexes, L-Methionylglycine 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-1501.pdf 
 Identifier    ZNB-1998-53b-1501 
 Volume    53 
8Author    Katharina Haas, Heinrich Nöth, Wolfgang Beck, *. Sonderdruckanforderungen, ProfW. Beck, HerrnRequires cookie*
 Title    Metallkomplexe mit biologisch wichtigen Liganden, CXX [1]. Halbsandwich-Komplexe von Ruthenium(II) und Iridium(III) mit 3-(3-Pyridyl)-D-alaninat Metal Complexes of Biologically Important Ligands, CXX [1]. Half Sandwich Complexes of Ruthenium(II) and Iridium(III) with R-3-(3-Pyridyl)-D-alaninate  
 Abstract    The reactions of the chloro bridged complexes [(/?-cymene)RuCl2]2 and [(C5Me5)IrCl2]2 with the anion of 3-(3-pyridyl)-D-alanine (L) afford the N,O-chelate complexes (p-cymene)-Ru(L)(Cl) (1) and (C5Me5)Ir(L)(Cl) (2). Abstraction of chloride from 1 and 2 using AgSbF6 gives the dimers [(p-cymene)Ru(^-L)2Ru(p-cymene)]2+(SbF6)2 (3) and [(C5Me5)Ir(/x-L)2-Ir(C5Me5)]2+(SbF6)2 (4) with coordination of the pyridine N atom. Complex 4 is formed in high diastereomeric excess. The structure of (C5Me5)Ir(^-L)2Ir(C5Me5)]Cl2 (5) which contains the SIrRcRc RIr diastereoisomer in the crystal was determined by X-ray diffraction. 
  Reference    Z. Naturforsch. 54b, 989—992 (1999); eingegangen am 23. April 1999 
  Published    1999 
  Keywords    Ruthenium, Iridium Complexes, 3-(3-Pyridyl)alanine 
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 TEI-XML for    default:Reihe_B/54/ZNB-1999-54b-0989.pdf 
 Identifier    ZNB-1999-54b-0989 
 Volume    54 
9Author    Wolfgang Weigand, Ulrich Nagel, Wolfgang BeckRequires cookie*
 Title    Pseudohalogeno-Metallverbindungen, LXVIII [1] Reaktionen der Cyanometallsäuren NCAuCNH  
 Abstract    , (NC) 4 Pt(CNH) 2 , (NC) 2 M(CNH) 4 (M = Fe, Ru, Os) undCo[bis(dimethyIglyoximato)](CN)CNHmit Epoxiden: 2-Hydroxyalkylisocyanid-und Oxazolidin-2-yIiden-MetalIkomplexe Pseudohalogeno Metal Compounds, LXVIII [1] Reaction of Cyano Metal Acids NCAuCNH, (NC) 4 Pt(CNH) 2 , (NC) 2 M(CNH) 4 (M = Fe, Ru, Os) and Co[bis(dimethylglyoximato)](CN)CNH with Epoxides: 2-Hydroxyalkylisocyanide and Oxazolidine-2-ylidene Metal Complexes NCAuCNH reacts with expoxides to give oxazolidine-2-ylidene (2) and 2-hydroxyalkyl com-plexes (3), respectively. Complexes with cyclic carbene ligands (NC) 4 Pt(-C-O —C—C-NH) 2 (5) and (NC)(Hdmg) 2 Co-C-O-C-C-NH (7) are formed from the corresponding isocyanic metal compounds and oxiranes. 5b has been characterized by crystal structure determination. Ring opening of phenyloxirane occurs at the phenyl substituted carbon atom. (NC) 2 M(CNH) 4 (M = Fe, Ru, Os) and oxirane yield mixtures of (NC) 2 M(—CN—C—C—OH) 4 and (NC) 2 M[—CN—C—C—(—O—C—C—)"—O—C—C—OH] 4 . 
  Reference    Z. Naturforsch. 43b, 328—338 (1988); eingegangen am 6. November 1987 
  Published    1988 
  Keywords    Ruthenium, Osmium, Cobalt Complexes of Isocyanic, 2-Hydroxyalkylisocyanide, Cyclic Aminooxycarbene 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0328.pdf 
 Identifier    ZNB-1988-43b-0328 
 Volume    43 
10Author    Anton Jungbauer, Helmut BehrensRequires cookie*
 Title    Über neue Carbamoyl-carbonyl-Komplexe des Eisens, Rutheniums und Osmiums [1] About New Carbamoyl Carbonyl Complexes of Iron, Ruthenium and Osmium [1]  
  Reference    Z. Naturforsch. 34b, 1641—1645 (1979); eingegangen am 3. August 1979 
  Published    1979 
  Keywords    Carbamoyl Carbonyl Phosphane Halogeno Metal( + II) Complexes, Iron, Ruthenium, Osmium, Carbamoyl Carbonyl Nitrosyl Phosphane Osmium(O) 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-1641.pdf 
 Identifier    ZNB-1979-34b-1641 
 Volume    34 
11Author    Azaborolinyl, G. Ünter Schmid, O. Ttm Ar Boltsch, D. Ieter Bläser, Roland BoeseRequires cookie*
 Title    Azaborolinyl-Komplexe, XV [1] Bis(f/5-l,2-azaborolinyI)ruthenium-Sandwichkomplexe — Darstellung und Strukturuntersuchung  
 Abstract    The synthesis of bis(l-rer?-butyl-2 -methyl-?75-l , 2 -azaborolinyl)ruthenium (1) and bis(2-methyl-l-trimethylsilyl-^5-l , 2 -azaborolinyl)ruthenium (2) succeeds when RuCL is reacted with the cor­ responding 1,2-azaborolinyl lithium compounds in THF at —70 °C. Each of the sandwich complex forms two isomers with a clockwise and an anti-clockwise conformation of the azaborolinyl rings. The anti-clockwise isomer of 1 (la) gives colourless crystals which were investigated by single­ crystal X-ray diffraction methods. The molecular structure shows the rings in an eclipsed orienta­ tion forming an interplanar angle of 8 .6 °. The isomers of 1 as well as of 2 give different 'H and "B NMR signals. 
  Reference    Z. Naturforsch. 39b, 1082 (1984); eingegangen am 4. Februar 1984 
  Published    1984 
  Keywords    Com plexes, XV [1] Bis(/;:'-l, 2-azaborolinyl)ruthenium Sandwich Complexes — Synthesis and Structure Investigation Azaborolinyl Sandwich Complex, Ruthenium, X-Ray, UB NMR Spectra, 'H NMR Spectra 
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 TEI-XML for    default:Reihe_B/39/ZNB-1984-39b-1082.pdf 
 Identifier    ZNB-1984-39b-1082 
 Volume    39