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1	Author	WolfdieterA. Schenk, Thom As Stur	Requires cookie*
	Title	Elektronenreiche Ruthenium-Thiolat-Komplexe, Synthese und Reaktionen mit Elektrophilen Electron-Rich Ruthenium Thiolate Complexes, Synthesis and Reactions with Electrophiles
	Abstract	Ruthenium thiolates [cpRu(PR'3)2(SR)] (PR ' 3 = PPh3, 1/2 dppe, 1/2 dppm, R = Me, C H 2Ph) are obtained from the corresponding chlorides and N aSR. PPh3 is readily exchanged for CO to give the chiral complexes [cpRu(PPh3)(CO)(SR)]. Alkylation with methyl tosylate yields the cations [cpRu(dppe)(SM eR)]+ and [cpRu(PPh3)(CO)(SM eR)]+, which were isolated as their PF6-salts. The neutral carbonyls add dimethyi acetylenedicarboxylate giving five-membered metallocycles.
	Reference	Z. Naturforsch. 45b, 1495—1498 (1990); eingegangen am 6. Juni 1990
	Published	1990
	Keywords	Ruthenium Complexes, Thiolate Complexes, Cycloaddition
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	TEI-XML for	default:Reihe_B/45/ZNB-1990-45b-1495.pdf
	Identifier	ZNB-1990-45b-1495
	Volume	45

2	Author	Ekkehard Lindner, Berthold Karle	Requires cookie*
	Title	Fluktuierendes Verhalten von Tris(Ether-Phosphan)-Ruthenium(II)- Komplexen Novel Basic Ligands for the Hom ogenous Catalytic C arbonylation of M ethanol, XXVII [1] Fluxional Behaviour of Tris(ether-phosphane) Ruthenium (II) Complexes
	Abstract	Three equivalents o f the ether-phosphane li gands 2 a -c react with Cl2R u(PPh3)3 (1) to give the complexes rra«.s-Cl2R u (P '''0)(P ~ 0) 2 (3a-c)
	Reference	Z. Naturforsch. 45b, 1108—1110 (1990); eingegangen am 24. Januar 1990
	Published	1990
	Keywords	Ruthenium Complexes, Ether-phosphanes, Fluxional Behaviour
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	TEI-XML for	default:Reihe_B/45/ZNB-1990-45b-1108_n.pdf
	Identifier	ZNB-1990-45b-1108_n
	Volume	45