| 1 | Author
| WolfdieterA. Schenk, Thom As Stur | Requires cookie* | | Title
| Elektronenreiche Ruthenium-Thiolat-Komplexe, Synthese und Reaktionen mit Elektrophilen Electron-Rich Ruthenium Thiolate Complexes, Synthesis and Reactions with Electrophiles  | | | Abstract
| Ruthenium thiolates [cpRu(PR'3)2(SR)] (PR ' 3 = PPh3, 1/2 dppe, 1/2 dppm, R = Me, C H 2Ph) are obtained from the corresponding chlorides and N aSR. PPh3 is readily exchanged for CO to give the chiral complexes [cpRu(PPh3)(CO)(SR)]. Alkylation with methyl tosylate yields the cations [cpRu(dppe)(SM eR)]+ and [cpRu(PPh3)(CO)(SM eR)]+, which were isolated as their PF6-salts. The neutral carbonyls add dimethyi acetylenedicarboxylate giving five-membered metallocycles. | | |
Reference
| Z. Naturforsch. 45b, 1495—1498 (1990); eingegangen am 6. Juni 1990 | | |
Published
| 1990 | | |
Keywords
| Ruthenium Complexes, Thiolate Complexes, Cycloaddition | | |
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| default:Reihe_B/45/ZNB-1990-45b-1495.pdf | | | Identifier
| ZNB-1990-45b-1495 | | | Volume
| 45 | |
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