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'Rubidiumtrimolybdatosulfate' in keywords Facet   Publication Year 1979  [X]
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1979[X]
1Author    Joachim Fuchs, Hans-Ulrich Kreusler, Achim FörsterRequires cookie*
 Title    Die Kristallstruktur des Rubidiumtrimolybdatosulfats Rb2SMo3013 The Structure of the Rubidiumtrimolybdatosulfate Rb2SMo30i3  
 Abstract    By acidification of an aqueous solution of Rb2MoÜ4 with sulfuric acid the rubidium trimolybdatosulfate Rb2SMo30i3 • 0.72 H20 is formed. A compound with the same composition and evidently the same structure but free of crystal water is obtainable by melting a mixture of Rb2SC>4 and M0O3 in molar ratios 1:3. The X-ray structure in-vestigation shows the anion to be built up from double chains of MoOß octahedra. Always three neighbouring octahedra are linked about common vertices with one SO4 tetrahedron. The tetrahedra are alternating above and below the double chain. -Rb2SMo30i3 is the first known macromolecular heteropolymolybdate. 
  Reference    Z. Naturforsch. 34b, 1683—1685 (1979); eingegangen am 6. August 1979 
  Published    1979 
  Keywords    Heteropolysulfate, Rubidiumtrimolybdatosulfate, X-ray, Vibrational Spectra 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-1683.pdf 
 Identifier    ZNB-1979-34b-1683 
 Volume    34