| | 1 | Author
| W. S. Sheldrick, B. Schaaf | Requires cookie* | | | Title
| Schichtstruktur £, [Te6~] RbTe6, a Polytelluride with Layer Structure ^,[Te6_]  | | | | Abstract
| Reaction of Rb2C 0 3 with Te in M ethanol at 160 °C in the presence of G e yields the polytellu ride RbTe6, the structure o f which has been deter mined by X-ray structural analysis. The poly anions (£,[Te6~] contain Te6 rings with a chair conformation, which are connected via four T e-T e bonds into a layer structure. A T structure is exhibited by the resulting TeTe3 units. The Rb cations adopt positions betw een neighbouring parallel anion layers and are surrounded by 12 Te atoms in their first coordination sphere. | | | |
Reference
| Z. Naturforsch. 49b, 993—9 (1994) | | | |
Published
| 1994 | | | |
Keywords
| Rubidium Polytelluride, Methanolothermal Synthesis, Crystal Structure | | | |
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| default:Reihe_B/49/ZNB-1994-49b-0993_n.pdf | | | | Identifier
| ZNB-1994-49b-0993_n | | | | Volume
| 49 | |
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