| 1 | Author
| Wolfgang Danzer, Wolfgang Beck, Michael Keubler | Requires cookie* | | Title
| Reaktionen von Metallcarbonylverbindungen mit Diaziridin 1 Reactions of Metal Carbonyls with Diaziridine  | | | Abstract
| Cyclic carbamoyl complexes (2) and (3) result from the reaction of metal carbonyl hydrides with 3,3-pentamethylen diaziridine (1). 1 is cleaved at the metal by reaction with substituted metal carbonyls of Mo and W formally into 'nitrene' and cyclohexanone imine, which are isolated as isocyanate and ketimine complexes, respectively. 1 forms adducts with cobalt and nickel(II) chlorides. | | |
Reference
| (Z. Naturforsch. 31b, 1360—1366 [1976]; eingegangen am 16. Juli 1976) | | |
Published
| 1976 | | |
Keywords
| Ring Opening, Diaziridine, Metal Carbonyls, Carbamoyl, Ketimine Complexes | | |
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| default:Reihe_B/31/ZNB-1976-31b-1360.pdf | | | Identifier
| ZNB-1976-31b-1360 | | | Volume
| 31 | |
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