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'Ring O pening and Closure' in keywords Facet   section ZfN Section B  [X]
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1986 (1)
1Author    WolfPeter Fehlhammer, Eberhard Bär, Borislav BoyadjievRequires cookie*
 Title    Chemie der Isoblausäure  
 Abstract    , II [1] Reaktionen von [M(CO)5CNH] (M = Cr, Mo, W) mit Aziridinen: Zyklische Diaminocarbenkomplexe Chemistry of Hydrogen Isocyanide, II [1] Reactions of [M(CO)5CNH] (M = Cr, Mo, W) with Aziridines: Cyclic Diaminocarbene Complexes The hydrogen isocyanide com plexes [M (C O)5CNH] (M = Cr, M o, W) have been treated with the aziridines R N C H R 'C H 2 (R = H, R' = H, Me, Et; R = M e, R' — H) to give im idazolidin-2-ylidene com plexes. The sam e type of ligand forms on addition of aziridine to the electrophilic isocyanide group in [FpC N Ph]+ in the presence of B r'. IR, 'H N M R , 13C N M R and mass spectra of the new com pounds are reported. 
  Reference    Z. Naturforsch. 41b, 1023—1027 (1986); eingegangen am 14. April 1986 
  Published    1986 
  Keywords    Functionalized Isocyanides, Reactions at Coordinated Ligands, Ring O pening and Closure, Carbene C om plexes 
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 TEI-XML for    default:Reihe_B/41/ZNB-1986-41b-1023.pdf 
 Identifier    ZNB-1986-41b-1023 
 Volume    41