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Title | Radiation Chemistry of DNA-Model Compounds, VII* On the Formation of 5-Deoxy-D-erythro-pentos- 4-ulose and the Identification of Twelve Further Products from y-Irradiated Aqueous Solutions of Ribose-5-phosphate ![]() | ||
Abstract | L o t h a k S t e l t e r , C l e m e n s v o n S o n n t a g , a n d D i e t r i c h S c h u l t e -F r o h l i n d e Different mechanisms are considered to explain the formation of 5-deoxy-D-erythro-pentos-4-ulose in the y-radiolysis of ribose-5-phosphate in aqueous solution. On the basis of deuterium labelling experiments one mech anism involving an enol as an intermediate could be excluded. The identification of twelve further radio-lysis products from ribose-5-phosphate is reported. | ||
Reference | (Z. Naturforsch. 30b, 656—657 [1975]; received February 19 1975) | ||
Published | 1975 | ||
Keywords | y-Radiolysis, Ribose-5-phosphate, Carbohydrates, Radical Reactions, Radical Cations | ||
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