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'Rhodium Complexes with Monomeric and Dimeric Fulvene Ligands' in keywords
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1983 (1)
1Author    Jörn Müller, Rainer Stock, Joachim PickardtRequires cookie*
 Title    Complex Formation of Rhodium with 6.6-Dimethylfulvene  
 Abstract    Reaction of [(nbd)RhCl]2 (nbd = nor bornadiene) with CH3Li and 6.6-dimethylfulvene yields (nbd)Rh(2-propenylcyclopentadienyl). (cod)Rh(Cl)P(CH3)3 (cod = 1.5-cycloocta-diene), obtained by cleavage of [(cod)RhCl]2 with P(CH3)3, reacts with 6.6-dimethyl-fulvene and CH3Li or i-C3Ü7MgBr with substitution of cod by dimeric fulvene ligands the nature of which depends on the alkyl reagent. The new complexes were characterized by NMR spectra and in one case by X-ray diffraction analysis. 
  Reference    Z. Naturforsch. 38b, 1454—1459 (1983); eingegangen am 28. Juni 1983 
  Published    1983 
  Keywords    Rhodium Complexes with Monomeric and Dimeric Fulvene Ligands, Synthesis, NMR Spectra, X-Ray 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-1454.pdf 
 Identifier    ZNB-1983-38b-1454 
 Volume    38