Go toArchive
Browse byFacets
Bookbag ( 0 )
'Rhenium VII Nitride Chloride' in keywords Facet   Publication Year 1979  [X]
Results  1 Item
Sorted by   
Section
Publication Year
1979[X]
1Author    Werner Liese, Kurt Dehnicke, Ingeborg Walker, Joachim SträhleRequires cookie*
 Title    Darstellung, Eigenschaften und Kristallstruktur von Rhenium(VII)-Nitridchlorid, ReNCl4 Preparation, Properties and Crystal Structure of Rhenium(VII) Nitride Chloride, ReNCU  
 Abstract    Rhenium(VII) nitride chloride, ReNCU, is prepared by the reaction of ReClö with nitrogen trichloride. It forms metallic glazing, hygroscopic needles with an effective magnetic moment of 0.23 B.M. In the mass spectrum only the molecular ion ReNCU® is present, followed by ReNCl3®. The crystal structure was determined by X-ray diffraction methods (space group II, 265 independent reflexions, R = 0.071). The structure consists of ReNCL units, which are linked by strongly alternated Re = N-Re chains with different bond lengths of r Re = N = 158 pm and r Re-N = 248 pm. The structure is very similar to that of WOCl4. 
  Reference    Z. Naturforsch. 34b, 693—696 (1979); eingegangen am 27. Februar 1979 
  Published    1979 
  Keywords    Rhenium(VII) Nitride Chloride, Preparation, IR, Magnetic Moment, Crystal Structure 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-0693.pdf 
 Identifier    ZNB-1979-34b-0693 
 Volume    34