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'Rhenium Complexes' in keywords Facet   Publication Year 1985  [X]
Facet   section ZfN Section B  [X]
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1Author    Udo Kunze, Andreas BrunsRequires cookie*
 Title    Phosphinsubstituierte Chelatliganden, XII [1] Metallinduzierte E/Z-Isomerisierung an Rheniumcarbonyl-Komplexen mit Phosphinothioformamid-und -thioformimidat-Liganden Phosphine-Substituted Chelate Ligands, XII [1] Metal-Induced E/Z-Isomerisation of Rheniumcarbonyl Complexes with Phosphino- thioformamide and -thioformimidate Ligands  
 Abstract    The coordination of tertiary phosphinothioform-amides and the isomeric S-alkyl phosphinothioform-imidates to BrRe(CO) 5 gives the /ac-bromotricar-bonylrhenium complexes la, b and 2a, b with P,S-chelate ligands. Unlike the analogous manganese complexes, the NMR spectra of dissolved lb and 2a, b show a splitting of the N-alkyl ('H, 13 C) and phosphorus signals indicating E/Z isomerisation of the ligands. 
  Reference    (Z. Naturforsch. 40b, 127—128 [1985]; eingegangen am 7. August/5. September 1984) 
  Published    1985 
  Keywords    E/Z-Isomerisation, NMR Spectra, Rhenium Complexes, Tertiary Phosphinothioform-amides, S-Alkyl Phosphinothioformimidates 
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 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-0127_n.pdf 
 Identifier    ZNB-1985-40b-0127_n 
 Volume    40