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'Rhenium Complexes' in keywords Facet   Publication Year 1981  [X]
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1Author    Udo Kunze, Antonios AntoniadisRequires cookie*
 Title    Phosphinsubstituierte Chelatliganden, II [1] Thiocarbamoylphosphinsulfid-und -oxid-Komplexe des Mangans und Rheniums Phosphine Substituted Chelate Ligands, II [1] Thiocarbamoylphosphine Sulfide and Oxide Complexes of Manganese and Rhenium  
 Abstract    Thiocarbamoylphosphine sulfides la-c and oxides 2a-c are ambidentate chelating ligands which may form monomeric or dimeric complexes with carbonylmetal halides. The reaction of la-c with ClMn(CO)s and ClRe(CO)s yields the monomeric cw-tetracarbonyl complexes 3a-c and 4a-c with S,S'-coordination. The phosphine oxides 2a-c first form tetracarbonyl complexes which dimerize spontaneously under loss of CO to give the anfi-/ac-tricarbonyl complexes 6a-c and 6 a with bridging three-coordinate sulfur. On refluxing in n-hexane solution, 8a-c and 4b, c are converted into the corresponding dimers 7a-c and 8 b, c. Dissolving of 7 b, c in CH2C12 leads to re-formation of 8 b, c, the free ligands lb, c and inorganic manganese compounds. 
  Reference    Z. Naturforsch. 36b, 1117—1124 (1981); eingegangen am 21. Mai 1981 
  Published    1981 
  Keywords    Chelate Ligands, Thiocarbamoylphosphine Sulfide, Thiocarbamoylphosphine Oxide, Manganese Complexes, Rhenium Complexes 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-1117.pdf 
 Identifier    ZNB-1981-36b-1117 
 Volume    36