| | 1 | Author
| Ekkehard Lindner, Günter Von Au | Requires cookie* | | | Title
| Darstellung und Eigenschaften von und Reaktionen mit metallhaltigen Heterocyclen, VII [1] Heterolytische Spaltung der Re-Re-Bindung in den Zweikern-Anionen [(OC)4ReP(R2 )0] 2 2 ~ mit Elektrophilen - ein Weg zu Heterocyclen mit Re-C-o-Bindung Preparation and Properties of, and Reactions with, Metal-Containing Heterocycles, VII [1] Heterolytic Cleavage of the Re-Re Bond in the Binuclear Anions [(0C)4ReP(R2)0]2 2_ with Electrophiles -a Pathway to Heterocycles with Re-C a Bonds  | | | | Abstract
| The preparation of the six-membered rhenacyclohexanes (OC)4ReP(R2)OCH2C(CH3)2CH2 (la, b) [R = CH3 (a), C6H5 (b)J is accomplished by heterolytic cleavage of the Re-Re bond in the binuclear anions [(0C)4ReP(R2)0]2 2 -with strong electrophiles like the alkane-diylbis(triflate) (CH3)2C(CH2Y)2 (Y= OSO2CF3), followed by an attack of the a>-positioned carbenium-like C atom on the phosphinite oxygen of the anion. 1 a, b insert SO2 under ring I I | | | |
Reference
| Z. Naturforsch. 35b, 1104—1110 (1980); eingegangen am 9. Mai 1980 | | | |
Published
| 1980 | | | |
Keywords
| Rhenacyclohexanes, Mechanism, S02-Insertio", X-ray, IR spectra, NMR spectra : | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/35/ZNB-1980-35b-1104.pdf | | | | Identifier
| ZNB-1980-35b-1104 | | | | Volume
| 35 | |
|
