Go toArchive
Browse byFacets
Bookbag ( 0 )
'Rhenacyclohexanes' in keywords Facet   Publication Year 1980  [X]
Facet   section ZfN Section B  [X]
Results  1 Item
Sorted by   
Publication Year
1980[X]
1Author    Ekkehard Lindner, Günter Von AuRequires cookie*
 Title    Darstellung und Eigenschaften von und Reaktionen mit metallhaltigen Heterocyclen, VII [1] Heterolytische Spaltung der Re-Re-Bindung in den Zweikern-Anionen [(OC)4ReP(R2 )0] 2 2 ~ mit Elektrophilen - ein Weg zu Heterocyclen mit Re-C-o-Bindung Preparation and Properties of, and Reactions with, Metal-Containing Heterocycles, VII [1] Heterolytic Cleavage of the Re-Re Bond in the Binuclear Anions [(0C)4ReP(R2)0]2 2_ with Electrophiles -a Pathway to Heterocycles with Re-C a Bonds  
 Abstract    The preparation of the six-membered rhenacyclohexanes (OC)4ReP(R2)OCH2C(CH3)2CH2 (la, b) [R = CH3 (a), C6H5 (b)J is accomplished by heterolytic cleavage of the Re-Re bond in the binuclear anions [(0C)4ReP(R2)0]2 2 -with strong electrophiles like the alkane-diylbis(triflate) (CH3)2C(CH2Y)2 (Y= OSO2CF3), followed by an attack of the a>-positioned carbenium-like C atom on the phosphinite oxygen of the anion. 1 a, b insert SO2 under ring I I 
  Reference    Z. Naturforsch. 35b, 1104—1110 (1980); eingegangen am 9. Mai 1980 
  Published    1980 
  Keywords    Rhenacyclohexanes, Mechanism, S02-Insertio", X-ray, IR spectra, NMR spectra : 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-1104.pdf 
 Identifier    ZNB-1980-35b-1104 
 Volume    35