| | 1 | Author
| JaapN. Louwen, RonaldR. Andréa, DerkJ. Stufkens, Ad Oskam | Requires cookie* | | | Title
| He(I) and He(II) Photoelectron Spectra of M[Co(CO)4]2 and M[Mn(CO)5]2 Complexes (M = Zn, Cd, and Hg)  | | | | Abstract
| The He(I) and He(II) photoelectron spectra of M[Co(CO)4]2 and M[Mn(CO)ö]2 complexes (M = Zn, Cd, Hg) are reported. Bands attributable to metal-metal bonds, metal d-levels and CO orbitals are assigned in agreement with a semi-ionic model, i.e. M 2+ and [M'(CO)"] -. Relativistic effects prove to be important in assigning these ultraviolet photoelectron spectra. | | | |
Reference
| Z. Naturforsch. 37b, 711—717 (1982); received January 26 1982 | | | |
Published
| 1982 | | | |
Keywords
| Carbonyl Complexes, Metal-Metal Bonds, Mercury, Relativistic Effect | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/37/ZNB-1982-37b-0711.pdf | | | | Identifier
| ZNB-1982-37b-0711 | | | | Volume
| 37 | |
| 2 | Author
| JaapN. Louwen, RonaldR. Andréa, DerkJ. Stufkens, Ad Oskam | Requires cookie* | | | Title
| He(I) and He(II) Photoelectron Spectra of Some L3MCo(CO)4 Complexes (M = Si, Ge, Sn, Pb and L = Cl, Br and CH3) | | | | Abstract
| The He(I) and He(II) photoelectron spectra of L3MCo(CO)4 complexes (M = Si, Ge, Sn, and Pb and L = Cl, Brand CH3) are reported. Bands attributable to the metal-cobalt bond, cobalt 3d and CO orbitals are assigned in agreement with a qualitative MO model. Rela-tivistic effects and He(I)/He(II) intensity ratios prove to be important in assigning these ultraviolet photoelectron spectra. | | | |
Reference
| Z. Naturforsch. 38b, 194—202 (1983); received October 3 1982 | | | |
Published
| 1983 | | | |
Keywords
| Metal-Metal Bond, UPS, Cobalt Complexes, Relativistic Effects, Ionization Potentials | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/38/ZNB-1983-38b-0194.pdf | | | | Identifier
| ZNB-1983-38b-0194 | | | | Volume
| 38 | |
|
