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'Reduction' in keywords Facet   section ZfN Section B:Volume 040  [X]
Facet   Publication Year 1985  [X]
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1Author    Wolfgang KaimRequires cookie*
 Title    Zur Reaktion aromatischer Phosphanderivate mit Elektronen, III [1, 2] Phosphan-Borane, -Alane und -Gallane On the Reaction of Aromatic Phosphane Derivatives with Electrons, III [1, 2] Phosphane-Boranes, -Alanes, and -Gallanes  
 Abstract    The 1:2 molecular complexes formed from l,4-phenylenebis(dimethylphosphane) and boranes, trialkyl-aluminum and -gallium have been reduced by potassium in THF in the presence of a K + -complexing crown ether. The bis(borane) complex anion radicals proved to be quite persistent, whereas corresponding aluminum radical complexes could only be observed below 240 K. The bis(trimethylgallium) complex gave gallium metal on reduction with potassium. An ESR spectro-scopic comparison with the anion radicals of the free ligand, of corresponding chalcogenides, imines and phosphonium salts demonstrates negligible effects of P-complexation on the JI spin distribution but high sensitivity of the 31 P coupling constant towards coordination of electrophiles at the basic P(III) centers. 
  Reference    (Z. Naturforsch. 40b, 61—66 [1985]; eingegangen am 1. Oktober 1984) 
  Published    1985 
  Keywords    Molecular Complexes, Reduction, Anion Radicals, ESR Spectra 
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 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-0061.pdf 
 Identifier    ZNB-1985-40b-0061 
 Volume    40