ZfN: Search Results

1	Author	Alena Novoselova, Vladimir Shishkin, Vladimir Khokhlov	Requires cookie*
	Title	Redox Potentials of Samarium and Europium in Molten Lithium Chloride
	Abstract	The samarium (III)/(II) and europium (III)/(II) redox potentials in molten lithium chloride were measured using the direct potentiometric method in the temperature range from 923 to 1094 K. Glassy carbon was used as the indifferent working electrode, and the standard chlorine electrode as a reference. The total concentration of rare-earth chlorides dissolved in molten lithium chloride did not exceed 4.5 mol%.
	Reference	Z. Naturforsch. 56a, 754—756 (2001); received August 20 2001
	Published	2001
	Keywords	Molten Salts, Redox Potentials, Samarium Chlorides, Europium Chlorides, Lithium Chloride
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	TEI-XML for	default:Reihe_A/56/ZNA-2001-56a-0754.pdf
	Identifier	ZNA-2001-56a-0754
	Volume	56

2	Author	Alena Novoselova, Vladimir Khokhlov, Vladimir Shishkin	Requires cookie*
	Title	Thermodynamic Characteristics of Samarium and Europium Chlorides in Molten Alkali Metal Chlorides
	Abstract	The formal standard redox potentials of samarium (III)/(II) (EZmi+/ Smi+) and europium (III)/(II) (• £, £u3+/eu2+) *n molten alkali metal chlorides were measured potentiometrically against a reference chlorine electrode. The Gibbs energy changes and equilibrium constants for the reaction LnCl2(D + V2 Cl2(g) LnCl3(I) were calculated for the salt systems studied. The effect o f the cationic composition of the melt-solvent on the above thermodynamic characteristics is also reported.
	Reference	Z. Naturforsch. 56a, 837—840 (2001); received August 20 2001
	Published	2001
	Keywords	Thermodynamic Stability, Rare Earth Chlorides, Molten Alkali Metal Chlorides, Redox Potentials, Gibbs Energy Changes
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	TEI-XML for	default:Reihe_A/56/ZNA-2001-56a-0837.pdf
	Identifier	ZNA-2001-56a-0837
	Volume	56