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'Reactivity' in keywords Facet   Publication Year 1985  [X]
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1Author    Lothar WeberRequires cookie*
 Title    Übergangsmetall-Schwefelylid-Komplexe, XXII [1] Zur Reaktivität von DicarbonylnitrosyI-f/ 5 -thiacyclohexadienyl-l-oxid- Chromkomplexen gegenüber Phosphor-und Schwefelyliden Transition Metal Sulfur Ylide Complexes, XXII [1] Reactivity Studies of Dicarbonylnitrosyl-^-thiacyclohexadienyl-l-oxide Chromium Complexes with Phosphorus and Sulfur Ylides  
 Abstract    ?? 5 -Thiacyclohexadienyl-l-oxide chromium complexes 3a—d are generated by treatment of the 1-methyl-thiabenzene-l-oxide complexes la—d with Li[BHEt 3 ] and successive nitrosylation of the intermediates 2a—d. 3a—d react with Me 2 S(0) = CH 2 or Ph 3 P=CH 2 at a carbonyl ligand in an additon/transylidation process to yield the very sensitive products 5, 6a—d. 
  Reference    Z. Naturforsch. 40b, 373—379 (1985); eingegangen am 12. Oktober 1984 
  Published    1985 
  Keywords    Reactivity, ?; 5 -Thiacyclohexadienyl-l-oxide Complexes, Sulfur Ylides, Transylidation 
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 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-0373.pdf 
 Identifier    ZNB-1985-40b-0373 
 Volume    40