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'Reactivity' in keywords Facet   Publication Year 1980  [X]
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1Author    Michael Börner, Rainer Müller, Heimich VahrenkampRequires cookie*
 Title    Arsenverbrückte zweikernige Mn(CO)4Br-Komplexe Arsenic Bridged Dinuclear Mn(C0)4Br Complexes  
 Abstract    In Mn(CO)öBr one or two CO groups could be replaced by Me2AsCl. From Me2AsCl-Mn(CO)4Br with carbonyl metalates, or from Mn(CO)sBr with organometal dimethylarsenides, the arsenic bridged dinuclear complexes L"M-AsMe2-Mn(CO)4Br with L"M = CrCp(CO)3, MoCp(CO)3, WCp(CO)3, and Mn(CO)5 were obtained. Upon attempts to convert these to metal-metal bonded compounds the Cr-As-Mn complex decomposed whereas the Mn-As-Mn complex was spontaneously converted to (CO)4Mn|>AsMe2, //-Br]Mn(CO)4. 
  Reference    Z. Naturforsch. 35b, 1391—1394 (1980); eingegangen am 25. Juni 1980 
  Published    1980 
  Keywords    Ligand Bridged Dinuclear Complexes, Substitution, Reactivity 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-1391.pdf 
 Identifier    ZNB-1980-35b-1391 
 Volume    35