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1Author    Fritz Preuss, Willi Towae, Joachim WoitschachRequires cookie*
 Title    Darstellung und Reaktionen der Oxovanadin(V)-tricarboxylate Synthesis and Reactions of Oxovanadium(V) Tricarboxylates  
 Abstract    Monomeric oxovanadium(V) tricarboxylates VO(RCOO)3 are prepared by reaction of VOCI3 with an excess of silver carboxylate in CH2CI2 or by depolymerization of (V02RC00)n in carboxylic acid anhydride. Their properties are studied by IR and X H NMR spectroscopy as well as by chemical reactions such as thermolysis, solvolysis, redistribution and complex formation. The structure of 2,2'-dipyridyl and 1,10-phenanthroline complexes [VO(RCOO)3 • B] (B = C10H8N2, C12H8N2) has been found to be octahedral with meridional arrangement of the carboxylate ligands. Syntheses of Na[VO(CH3COO)4] and Ba[V02(CH3C00)3] • 2CH3COOH are described. 
  Reference    Z. Naturforsch. 35b, 817—823 (1980); eingegangen am 8. Oktober 1979/14. Januar 1980 
  Published    1980 
  Keywords    Oxovanadium(V) Tricarboxylates, Preparation, Reaction, iH NMR Spectra, IR Spectra 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0817.pdf 
 Identifier    ZNB-1980-35b-0817 
 Volume    35