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'Reactions at Coordinated Ligands' in keywords Facet   section ZfN Section B  [X]
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1994 (1)
1989 (2)
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1986 (1)
1Author    W. Olf, Peter Fehlhammer, Hans Hoffmeister, Borislav Boyadjiev, Thomas KolrepRequires cookie*
 Title    Bor-stabilisierte N,0-Carbene, II [1] Röntgenstrukturanalyse von (fra/i5-4,5-Dimethyloxazolidin-2-yliden)triphenylbor und N-Alkylierungen Boron Stabilized N,0-Carbenes, II [1] X-Ray Structure of (/rans-4,5-Dimethyloxazolidin-2-ylidene)triphenylboron and N-Alkylations  
 Abstract    The X-ray structure analysis of (?rartj,-4,5-dimethyloxazolidin-2-ylidene)triphenylboron reveals a stereochemistry of the carbene ligand which is almost identical with that in transition metal complexes. Deprotonation of triphenylboron stabilized oxazolidin-2-ylidenes with NaH leads to (oxazolin-2-ato)borates, which have been N-alkylated with [R30 +][BF4_] or R I under mild condi­ tions. 
  Reference    Z. Naturforsch. 44b, 917 (1989); eingegangen am 27. Dezember 1988/8. März 1989 
  Published    1989 
  Keywords    Non-Metal Stabilized Carbenes, Reactions at Coordinated Ligands, X-Ray Structure 
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 TEI-XML for    default:Reihe_B/44/ZNB-1989-44b-0917.pdf 
 Identifier    ZNB-1989-44b-0917 
 Volume    44 
2Author    WolfPeter Fehlhammer, Eberhard Bär, Borislav BoyadjievRequires cookie*
 Title    Chemie der Isoblausäure  
 Abstract    , II [1] Reaktionen von [M(CO)5CNH] (M = Cr, Mo, W) mit Aziridinen: Zyklische Diaminocarbenkomplexe Chemistry of Hydrogen Isocyanide, II [1] Reactions of [M(CO)5CNH] (M = Cr, Mo, W) with Aziridines: Cyclic Diaminocarbene Complexes The hydrogen isocyanide com plexes [M (C O)5CNH] (M = Cr, M o, W) have been treated with the aziridines R N C H R 'C H 2 (R = H, R' = H, Me, Et; R = M e, R' — H) to give im idazolidin-2-ylidene com plexes. The sam e type of ligand forms on addition of aziridine to the electrophilic isocyanide group in [FpC N Ph]+ in the presence of B r'. IR, 'H N M R , 13C N M R and mass spectra of the new com pounds are reported. 
  Reference    Z. Naturforsch. 41b, 1023—1027 (1986); eingegangen am 14. April 1986 
  Published    1986 
  Keywords    Functionalized Isocyanides, Reactions at Coordinated Ligands, Ring O pening and Closure, Carbene C om plexes 
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 TEI-XML for    default:Reihe_B/41/ZNB-1986-41b-1023.pdf 
 Identifier    ZNB-1986-41b-1023 
 Volume    41 
3Author    WolfPeter Fehlhammer, Thomas Bliß, Wilfried Sperber, Joachim FuchsRequires cookie*
 Title    Homoleptische Carbenkomplexe, V [1] Chelatartige Percarbenkomplexe des Palladiums und Platins Homoleptic Carbene Complexes, V [1] Chelating Percarbene Complexes of Palladium and Platinum  
 Abstract    Ten palladium and platinum complexes each containing two chelating bis(diaminocarbe-ne) ligands have been synthesized in a one pot-reaction from P dl2, P tl2 or K2PtCl4, a tenfold excess (forty equivalents) of isocyanide and 1,2-or 1,3-diamines. A n X-ray investigation of 
  Reference    Z. Naturforsch. 49b, 494—500 (1994); eingegangen am 10. N ovem ber 1993 
  Published    1994 
  Keywords    Isocyanide Complexes, Reactions at Coordinated Ligands, Chelating Bis(diam inocarbene) Ligands, X-Ray 
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 TEI-XML for    default:Reihe_B/49/ZNB-1994-49b-0494.pdf 
 Identifier    ZNB-1994-49b-0494 
 Volume    49 
4Author    WolfPeter Fehlhammer, Dagobert Achatz, Ulrike Plaia, Alfons VölklRequires cookie*
 Title    Metallkomplexe funktioneller Isocyanide, XIV [1] [3+2]-Cycloadditionen zwischen Metallo-Nitrilyliden und CS 2 und Carbenübertragung: Thiazolin-2-yliden-Komplexe von Chrom, Wolfram und Palladium Metal Complexes of Functional Isocyanides, XIV [1] [3+2] Cycloadditions between Metallo Nitrile Ylids and CS 2 and Carbene Transfer: Thiazoline-2-ylidene Complexes of Chromium, Tungsten and Palladium  
  Reference    Z. Naturforsch. 42b, 720—727 (1987); eingegangen am 26. Januar 1987 
  Published    1987 
  Keywords    a-Metalated Isocyanides, Reactions at Coordinated Ligands, Metals in Organic Synthesis, Carbenoid Heterocycles, X-Ray 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0720.pdf 
 Identifier    ZNB-1987-42b-0720 
 Volume    42 
5Author    WolfPeter Fehlhammer, Hans Hoffmeister, Heribert Stolzenberg, Borislav BoyadjievRequires cookie*
 Title    Bor-stabilisierte N,0-Carbene, I Triphenylbor-Addukte von Siloxy-und Hydroxyalkylisocyaniden und spontane At-YIid-Bildung Boron-Stabilized N.O-Carbenes, I Triphenylboron Adducts of Siloxy-and Hydroxyalkyl Isocyanides and Spontaneous Formation of Ate-Ylids  
  Reference    Z. Naturforsch. 44b, 419 (1989); eingegangen am 27. D ezem ber 1988 
  Published    1989 
  Keywords    Functionalized Isocyanides, Borane Isocyanide A dducts, Reactions at Coordinated Ligands, NO-H eterocycles, Carbene Complexes 
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 TEI-XML for    default:Reihe_B/44/ZNB-1989-44b-0419.pdf 
 Identifier    ZNB-1989-44b-0419 
 Volume    44