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'Reactions at Coordinated Ligands' in keywords Facet   Publication Year 1989  [X]
Facet   section ZfN Section B  [X]
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1989[X]
1Author    W. Olf, Peter Fehlhammer, Hans Hoffmeister, Borislav Boyadjiev, Thomas KolrepRequires cookie*
 Title    Bor-stabilisierte N,0-Carbene, II [1] Röntgenstrukturanalyse von (fra/i5-4,5-Dimethyloxazolidin-2-yliden)triphenylbor und N-Alkylierungen Boron Stabilized N,0-Carbenes, II [1] X-Ray Structure of (/rans-4,5-Dimethyloxazolidin-2-ylidene)triphenylboron and N-Alkylations  
 Abstract    The X-ray structure analysis of (?rartj,-4,5-dimethyloxazolidin-2-ylidene)triphenylboron reveals a stereochemistry of the carbene ligand which is almost identical with that in transition metal complexes. Deprotonation of triphenylboron stabilized oxazolidin-2-ylidenes with NaH leads to (oxazolin-2-ato)borates, which have been N-alkylated with [R30 +][BF4_] or R I under mild condi­ tions. 
  Reference    Z. Naturforsch. 44b, 917 (1989); eingegangen am 27. Dezember 1988/8. März 1989 
  Published    1989 
  Keywords    Non-Metal Stabilized Carbenes, Reactions at Coordinated Ligands, X-Ray Structure 
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 TEI-XML for    default:Reihe_B/44/ZNB-1989-44b-0917.pdf 
 Identifier    ZNB-1989-44b-0917 
 Volume    44 
2Author    WolfPeter Fehlhammer, Hans Hoffmeister, Heribert Stolzenberg, Borislav BoyadjievRequires cookie*
 Title    Bor-stabilisierte N,0-Carbene, I Triphenylbor-Addukte von Siloxy-und Hydroxyalkylisocyaniden und spontane At-YIid-Bildung Boron-Stabilized N.O-Carbenes, I Triphenylboron Adducts of Siloxy-and Hydroxyalkyl Isocyanides and Spontaneous Formation of Ate-Ylids  
  Reference    Z. Naturforsch. 44b, 419 (1989); eingegangen am 27. D ezem ber 1988 
  Published    1989 
  Keywords    Functionalized Isocyanides, Borane Isocyanide A dducts, Reactions at Coordinated Ligands, NO-H eterocycles, Carbene Complexes 
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 TEI-XML for    default:Reihe_B/44/ZNB-1989-44b-0419.pdf 
 Identifier    ZNB-1989-44b-0419 
 Volume    44