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1981 (1)
1Author    Alfred StaniendaRequires cookie*
 Title    Energiebilanz einer Reaktion zwischen Radikal-Kation und Radikal-Anion Energy Turnover of a Reaction between Radical Cation and Radical Anion  
 Abstract    AG for the reaction R ,+ + R-~ -> 2 R + AG was calculated according to AG = —(IP-EA) = —A Ei for the reaction in gas phase under ideal conditions. The result was compared with A H in solution measured calorimetrically and the entropy term measured voltammetrically according to AG = A H — TzlS. Both values for AG agreed satisfactorily. From this it was derived that the solvation energies of R ,+ and R— com-pensate mutually. The Coulomb energies have little influence on A G only. 
  Reference    Z. Naturforsch. 36b, 601—608 (1981); eingegangen am 29. Dezember 1980 
  Published    1981 
  Keywords    Radical Ions, Reaction Enthalpy, Ion Solvation, Energy Levels 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0601.pdf 
 Identifier    ZNB-1981-36b-0601 
 Volume    36