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'Radicals' in keywords Facet   section ZfN Section B:Volume 035  [X]
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1980 (1)
1Author    Norio Miyoshi, Giiti TomitaRequires cookie*
 Title    Fluorescein-photosensitized Furan Oxidation in Methanolic and Reversed Micellar Solutions, Part II Kinetic Analysis  
 Abstract    The 1,3-diphenylisobenzofuran oxidation was investigated in methanolic and dodecyl-ammonium propionate reversed micellar solutions using fluorescein sodium as photo-sensitizer. The furan oxidation was caused by the singlet oxygen mechanism (Type II). Aniline enhanced remarkably the furan oxidation in methanolic solutions, but inhibited highly this oxidation in the reversed micellar solutions. This enhancement of the furan oxidation was considered to be brought about by the occurrence of a radical mechanism (Type I) besides Type II mechanism. No Type I reaction occurred in the micellar solutions. The rate constants concerning with both reaction processes were evaluated by kinetic analysis, employing various aryl-and alkyl-amines. The reaction mechanism of Type I and the quenching mechanism of singlet oxygen by amines were discussed from the relationship between the rate constants, and the ionization potential of amines and the solvent polarity. 
  Reference    (Z. Naturforsch. 35b, 107—111 [1980]; received July 27 1979) 
  Published    1980 
  Keywords    Singlet Oxygen, Radicals, Fluorescein, Diphenylisobenzofuran, Reversed Micelles 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0107.pdf 
 Identifier    ZNB-1980-35b-0107 
 Volume    35