| | 1 | Author
| J. Nolte, J. Grußdorf, F. Temps, H. Gg, Wagner | Requires cookie* | | | Title
| Kinetics of the Reaction HOCO + 0 2 in the Gas Phase  | | | | Abstract
| Using the discharge flow method, the kinetics of the gas phase reaction HOCO + 0 2 products (1) was investigated at room temperature and pressures around p « 2.0 mbar with Far Infrared Laser Magnetic Resonance (FIR-LMR) detection of HOCO, H0 2 , and OH. From the measured concen-tration-versus-time decay profiles of HOCO in the absence and presence of a large excess of 0 2 , the overall rate constant of the reaction was found to be k, (296 K) = (9.9 ±1.5) • 10 11 cm 3 /mol • s. The main reaction channel, which leads to production of H0 2 + C0 2 , could be established. | | | |
Reference
| Z. Naturforsch. 48a, 1234—1238 (1993); received November 3 1993 | | | |
Published
| 1993 | | | |
Keywords
| Chemical kinetics, Gases, Radicals, Spectroscopy, Laser Magnetic Resonance | | | |
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| default:Reihe_A/48/ZNA-1993-48a-1234.pdf | | | | Identifier
| ZNA-1993-48a-1234 | | | | Volume
| 48 | |
| 2 | Author
| B. Kramer, J. Fleischhauer, J. Michl | Requires cookie* | | | Title
| Magnetischer Circular Dichroismus (MCD) von cyclischen rc-Elektronensystemen mit 4N±1 Elektronen | | | | Abstract
| The theory of the magnetic circular dichroism (MCD) of cyclic re-electron systems with 4 N ± 1 electrons, such as the radical anion of [16] annulene, has been investigated in the perimeter model approximation. General solutions and formulas for the calculation of the Faraday parameters A, B, and C are derived analytically. The calculated and measured spectra of the 17 re-electron [16] annulene radical are in good agreement. | | | |
Reference
| Z. Naturforsch. 48a, 1243—1255 (1993) | | | |
Published
| 1993 | | | |
Keywords
| Magnetic circular dichroism, Perimeter model, PPP method, re-Electron systems, Radicals | | | |
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| default:Reihe_A/48/ZNA-1993-48a-1243.pdf | | | | Identifier
| ZNA-1993-48a-1243 | | | | Volume
| 48 | |
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