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'Pyrrolidinium bis diisopropylphosphinoyl phosphide' in keywords
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1983 (1)
1Author    Dieter Weber, Karl Peters, Hans Georg, Schnering, Ekkehard FluckRequires cookie*
 Title    Kristallstruktur yon Pyrrolidinium-bis(diisopropylphosphinoyl)phosphid, einem System mit zweifach koordiniertem Phosphor Crystal Structure of Pyrrolidinium-bis(diisopropylphosphinoyl)phosphide, a System with Bicoordinated Phosphorus  
 Abstract    Pyrrolidinium-bis(diisopropylphosphinoyl)phosphide crystallizes triclinically in the space group Pi with a = 1019.6(8), b = 1271.5(4), c = 999.5(7) pm, a = 100.90(5)°, ß = 91.24(5)°, y = 99.10(5)° and Z = 2 formula units. The mean P-P bond length is 212.2 pm and hence shorter than in derivates in which the electron pairs of the bicoordi-nated phosphorus atom are bonded to one or two M(CO)5-groups. Additional p.-z-d* bonding explains the shortening of the P-P bond. 
  Reference    Z. Naturforsch. 38b, 208—211 (1983); eingegangen am 13. Oktober 1982 
  Published    1983 
  Keywords    Pyrrolidinium-bis(diisopropylphosphinoyl)phosphide, Crystal Structure, NMR Spectra 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0208.pdf 
 Identifier    ZNB-1983-38b-0208 
 Volume    38