| | 1 | Author
| Dieter Weber, Karl Peters, Hans Georg, Schnering, Ekkehard Fluck | Requires cookie* | | | Title
| Kristallstruktur yon Pyrrolidinium-bis(diisopropylphosphinoyl)phosphid, einem System mit zweifach koordiniertem Phosphor Crystal Structure of Pyrrolidinium-bis(diisopropylphosphinoyl)phosphide, a System with Bicoordinated Phosphorus  | | | | Abstract
| Pyrrolidinium-bis(diisopropylphosphinoyl)phosphide crystallizes triclinically in the space group Pi with a = 1019.6(8), b = 1271.5(4), c = 999.5(7) pm, a = 100.90(5)°, ß = 91.24(5)°, y = 99.10(5)° and Z = 2 formula units. The mean P-P bond length is 212.2 pm and hence shorter than in derivates in which the electron pairs of the bicoordi-nated phosphorus atom are bonded to one or two M(CO)5-groups. Additional p.-z-d* bonding explains the shortening of the P-P bond. | | | |
Reference
| Z. Naturforsch. 38b, 208—211 (1983); eingegangen am 13. Oktober 1982 | | | |
Published
| 1983 | | | |
Keywords
| Pyrrolidinium-bis(diisopropylphosphinoyl)phosphide, Crystal Structure, NMR Spectra | | | |
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| default:Reihe_B/38/ZNB-1983-38b-0208.pdf | | | | Identifier
| ZNB-1983-38b-0208 | | | | Volume
| 38 | |
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