1 | Author | Stefan Sawusch, Uwe Schilde | Requires cookie* |
Title | Ligandenaustauschreaktionen von NiCl2(PPh3)2 mit 0(S)~N~S-Liganden Ligand Exchange Reactions of NiCl2(PPh3)2 with 0 (S )^ N ^ S Ligands ![]() | ||
Abstract | Ligand exchange reactions of NiCl2(PPh3)2 with O (S)'"'N ^ S ligands were studied. Oxi dation products of O^N^S ligands have been characterized and their structures deter mined: 3-methyl-4H-benzo[b] [ 1,4]thiazin-2-yl-phenylmethanone / 2-methyl-benzo[d] [ 1,3]thi-azole (mixed crystal); [2-iminoisopropyl-thiophenolato(2-)](triphenyl-phosphane)-nickel(II); 1 -phenyl-3-methyl-4-(benzoyl-thiobenzoylhydrazono)-pyrazol-5-thione; [ 1 -phenyl-3-methyl-4-(benzoyl-thiobenzoylhydrazono)-pyrazol-5-thionato](triphenyl-phosphane)-nickel(II). | ||
Reference | Z. Naturforsch. 54b, 881—886 (1999); eingegangen am 9. März 1999 | ||
Published | 1999 | ||
Keywords | Nickel Chelates, Ligand Exchange Reactions, Benzothiazine, Benzothiazole, Pyrazolone | ||
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