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1996 (1)
1Author    H. Möhrle, U. Von Der Lieck-WaldheimRequires cookie*
 Title    Vinamidinium-Salze als Nucleophile Vinamidinium Salts as N ucleophiles  
 Abstract    1,4-diazepinium salts could not be aminomethylated with conventional methods, but the hydrochlorides produced with methyleniminium salts the C-Mannich-compounds. The reactivity of the substrate was mainly controlled by electronic effects of the substituents. Aminomethylation of 1,5-diazapentadienium salts occurred only if the conformations caused no steric hindrance of the ß-C-atom. Methyl substituted 2,3-dihydro-1,4-diazepinium salts reacted with 1,3,5 triazine to pyrimidine anellated derivatives. 
  Reference    Z. Naturforsch. 51b, 421—430 (1996); eingegangen am 4. Juli 1995 
  Published    1996 
  Keywords    Mannich Reaction, Iminium Salts, 1, 3, 5 Triazine, Push-Pull-Systems 2, 3-Dihydro- 
  Similar Items    Find
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0421.pdf 
 Identifier    ZNB-1996-51b-0421 
 Volume    51