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'Pseudohalogens' in keywords Facet   section ZfN Section B  [X]
Facet   Publication Year 1982  [X]
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1Author    Moisés Morán, Augusto Ibáñez, J. R. MasaguerRequires cookie*
 Title    Reactions of r/-C5H5Co(CO)2 and ^-Me3SiC5H4Co(CO)2 with (XCN)2 and X(CN)2 (X = S or Se)  
 Abstract    The pseudohalogens (XCN) 2 (X = S or Se) react with ^-C5H 5 Co(CO)2 and 7;-Me3SiC5H4Co(CO)2 with formation of the 18 electron complexes, RCo(CO)(XCN)2 (R = r]-C5H5 or ^-MeßSiCsBU). By reactions with X(CN)2 (X = S or Se), the cyclopentadienyl cobalt dicarbonyls are transformed into the mixed complexes, RCo(CO)(CN)(XVN) (R = ^-CÖHÖ or ^-MesSiCsH^. All the compounds are characterized by elemental analysis, IR, electronic and 1 H NMR spectra. The thiocyanogen derivatives undergo linkage isomerism (N->S) in polar solvents. 
  Reference    Z. Naturforsch. 37b, 292—298 (1982); received September 21/November 9 1981 
  Published    1982 
  Keywords    Pseudohalogens, Electron Complexes, 1 H NMR Spectra 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-0292.pdf 
 Identifier    ZNB-1982-37b-0292 
 Volume    37