| | 1 | Author
| Moisés Morán, Augusto Ibáñez, J. R. Masaguer | Requires cookie* | | | Title
| Reactions of r/-C5H5Co(CO)2 and ^-Me3SiC5H4Co(CO)2 with (XCN)2 and X(CN)2 (X = S or Se)  | | | | Abstract
| The pseudohalogens (XCN) 2 (X = S or Se) react with ^-C5H 5 Co(CO)2 and 7;-Me3SiC5H4Co(CO)2 with formation of the 18 electron complexes, RCo(CO)(XCN)2 (R = r]-C5H5 or ^-MeßSiCsBU). By reactions with X(CN)2 (X = S or Se), the cyclopentadienyl cobalt dicarbonyls are transformed into the mixed complexes, RCo(CO)(CN)(XVN) (R = ^-CÖHÖ or ^-MesSiCsH^. All the compounds are characterized by elemental analysis, IR, electronic and 1 H NMR spectra. The thiocyanogen derivatives undergo linkage isomerism (N->S) in polar solvents. | | | |
Reference
| Z. Naturforsch. 37b, 292—298 (1982); received September 21/November 9 1981 | | | |
Published
| 1982 | | | |
Keywords
| Pseudohalogens, Electron Complexes, 1 H NMR Spectra | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/37/ZNB-1982-37b-0292.pdf | | | | Identifier
| ZNB-1982-37b-0292 | | | | Volume
| 37 | |
|
