ZfN: Search Results

1	Author	M. Bobadilla, M. Morán	Requires cookie*
	Title	Oxidative Addition of Pseudohalogen to [P(OPh)3]4Ni
	Abstract	The title compound reacts with cyanogen halides, XCN (X = Br or I) to give the com-plexes L2(X)(CN)Ni (L = P(OPh)3, X = Br or I). The oxidative addition of (SCN)2 and (SeCN)2 to the same compound results in the formation of L2Ni(XCN)2 (X = S or Se). All the complexes have been characterized by elemental analysis, and IR, iH NMR and electronic spectra.
	Reference	Z. Naturforsch. 38b, 1069—1071 (1983); received May 13 1983
	Published	1983
	Keywords	Pseudohalogens, IR Spectra, Nickel
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	TEI-XML for	default:Reihe_B/38/ZNB-1983-38b-1069.pdf
	Identifier	ZNB-1983-38b-1069
	Volume	38

2	Author	Moisés Morán, Augusto Ibáñez, J. R. Masaguer	Requires cookie*
	Title	Reactions of r/-C5H5Co(CO)2 and ^-Me3SiC5H4Co(CO)2 with (XCN)2 and X(CN)2 (X = S or Se)
	Abstract	The pseudohalogens (XCN) 2 (X = S or Se) react with ^-C5H 5 Co(CO)2 and 7;-Me3SiC5H4Co(CO)2 with formation of the 18 electron complexes, RCo(CO)(XCN)2 (R = r]-C5H5 or ^-MeßSiCsBU). By reactions with X(CN)2 (X = S or Se), the cyclopentadienyl cobalt dicarbonyls are transformed into the mixed complexes, RCo(CO)(CN)(XVN) (R = ^-CÖHÖ or ^-MesSiCsH^. All the compounds are characterized by elemental analysis, IR, electronic and 1 H NMR spectra. The thiocyanogen derivatives undergo linkage isomerism (N->S) in polar solvents.
	Reference	Z. Naturforsch. 37b, 292—298 (1982); received September 21/November 9 1981
	Published	1982
	Keywords	Pseudohalogens, Electron Complexes, 1 H NMR Spectra
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	TEI-XML for	default:Reihe_B/37/ZNB-1982-37b-0292.pdf
	Identifier	ZNB-1982-37b-0292
	Volume	37