| | 1 | Author
| Bernd Ziegler, Michael Witzel, Martin Schwarten, Dietrich Babel | Requires cookie* | | | Title
| Neutronen-und Röntgenbeugungsuntersuchungen an Pulvern und Einkristallen von Strukturverwandten des Berliner Blaus: CsMnnCrln (CN)6 * D20 , NMe4MnII(Cr,M)6Mn0>»4)III(CN)6 * 8 H20 , NMe4MnIICoI1I(CN)6 * 8 H20 , Mn3ll[MnI1I(CN)6]2 * 15 H20 und Cd3[Fen l(CN)6]2 * 15 H20 Neutron and X-Ray Diffraction Studies on Powders and Single Crystals of Compounds Structurally Related to Prussian Blue: CsMn1ICrIII(CN)6 * D^O, NMe4MnII(Cr006Mn0 94)III(CN)6 * 8 H.O, NMe4MnnCoin(CN)6 * 8 H .O " Mn3II[MnIII(CN)6]2 * 15 H20 and Cd3[Fem(CN)6]2 * 15 H20  | | | | Abstract
| The results of a Rietveld refinement of CsMnCr(CN)6 • D20 neutron powder data (a = 1084.3(1) pm, F43m, Z = 4) and of a neutron single crystal structure refinement of tetragonal NMe4M nII(Cro.o6Mno.94)III(CN)6 • 8 H20 (a = 1065.8(21), c = 1064.6(26) pm, P4/n, Z = 2) at ambient temperature are reported. Single crystal X-ray analyses of the isostructural octahydrate NMe4M nCo(CN)6 • 8 H20 (a = 1062.1 (1), c = 1046.2(1) pm) and of gel-grown crystals of cubic M n31I[M nI1I(CN)6]2 -15 H20 (a = 1062.6(3) pm, Fm3m, Z = 4/3) and Cd3[Fe(CN)6]2 • 15 H20 (a = 1067.7(3) pm) were performed as well. The latter "Prussian Blues" are highly disordered and intermediate with respect to cyano-bridging between the above three-dimensional cesium and one-dimensional tetramethylammonium compounds. | | | |
Reference
| Z. Naturforsch. 54b, 870—876 (1999); eingegangen am 6. April 1999 | | | |
Published
| 1999 | | | |
Keywords
| Crystal Structure, Neutron Diffraction, Prussian Blue, Hexacyanometallate(III) | | | |
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| ZNB-1999-54b-0870 | | | | Volume
| 54 | |
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