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1984 (1)
1983 (1)
1Author    Hidenari Inoue, Ekkehard FluckRequires cookie*
 Title    Darstellung und Charakterisierung von Berlinerblau-Analoga des Typs Ti[MB(CN)6] Preparation and Characterization of Prussian Blue Analogs of the Type Ti[MB(CN)6]  
 Abstract    Three compounds of the type Ti[MB(CN)6] (MB = Co, Rh, and Ir) have been synthesized and characterized by means of their X-ray diffraction powder patterns, magnetic measurements, infrared, electronic, and X-ray photoelectron spectra. All compounds crystallize in the face-centered cubic system and form a three-dimensional framework of two octahedral coordination units MBC6 and TiN6. Upon the formation of Ti[MB(CN)6] from the corresponding potassium salt, the jz back-donation in the [MD(CN)6]3-moiety is enhanced by the bridge formation through the cyanide ligand. 
  Reference    Z. Naturforsch. 39b, 185 (1984); eingegangen am 12. Oktober 1983 
  Published    1984 
  Keywords    Preparation, Characterization, Prussian Blue Analogs 
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 TEI-XML for    default:Reihe_B/39/ZNB-1984-39b-0185.pdf 
 Identifier    ZNB-1984-39b-0185 
 Volume    39 
2Author    Hidenari Inoue, Ekkehard FluckRequires cookie*
 Title    Mößbauer-und Röntgenphotoelektronen-spektroskopische Untersuchungen an Berlinerblau-Analoga des Typs Fe[M B (CN)6] Mößbauer and X-Ray Photoelectron Spectroscopic Studies on Prussian Blue Analogs of the Type Fe[M B (CN)6]  
 Abstract    Prussian Blue analogs of the type Fe[M B (CN)e] (M B = Pd and Pt) crystallize in the face-centered cubic system: space group Fm3m-0^, Z = 4. Magnetochemical and Mößbauer spectroscopic measurements have revealed that nitrogen-coordinated iron(II) ions and carbon-coordinated M B (IV) ions are in the high spin state and in the low spin state, respectively, in the temperature range 4.2 to 300 K. Upon the formation of Fe[M B (CN)ß] from K2[M B (CN)6], the binding energies of N Is, Pd 3d5/2 and Pt 4f7/2 increase while the C 1 s binding energy decreases. This tendency could be interpreted in terms of the inductive effect of iron(II) ions attached to the nitrogen end of cyanide ligands. 
  Reference    Z. Naturforsch. 38b, 687—691 (1983); eingegangen am 7. Februar 1983 
  Published    1983 
  Keywords    Mößbauer Spectra, X-Ray Photoelectron Spectra, Prussian Blue Analogs 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0687.pdf 
 Identifier    ZNB-1983-38b-0687 
 Volume    38