Go toArchive
Browse byFacets
Bookbag ( 0 )
'Potassium Selenostannate IV' in keywords
Results  1 Item
Sorted by   
Section
Publication Year
1988 (1)
1Author    W. S. SheldrickRequires cookie*
 Title    Das kantenverknüpfte tritetraedrische Selenostannat(IV)-Anion [Sn 3 Se 8 ] 4 . Darstellung und Struktur von K 4 Sn 3 Se 8 The Edge-bridged Tritetrahedral Selenostannate(IV) Anion [Sn 3 Se 8 ] 4-. Preparation and Structure of K 4 Sn 3 Se 8  
 Abstract    The potassium selenostannate(IV) K4Sn3Ses has been prepared by methanolothermal reaction of K2C03 with elemental Sn and Se at 190 °C and its structure established by X-ray structural analysis. The unit cell contains isolated [Sn3Se8] 4-anions consisting of a central SnSe4-tetrahedron edge-bridged to two further tetrahedra. Crystallographic D2-symmetry is observed for these an-ions. The four-membered rings are markedly distorted with Sn —Se bond distances of 2.520(1) to the central tin atom as compared to long Sn-Se distances of 2.622(1) Ä to the tin atoms of the outer tetrahedra. The terminal Sn —Se bonds have a length of 2.473(1) Ä. 
  Reference    Z. Naturforsch. 43b, 249—252 (1988); eingegangen am 30. November 1987 
  Published    1988 
  Keywords    Potassium Selenostannate(IV), Methanolothermal Synthesis, Crystal Structure 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0249.pdf 
 Identifier    ZNB-1988-43b-0249 
 Volume    43