| | 1 | Author
| Helmut Behrens, Jochen Ellermann, EwaldF. Hohenberger | Requires cookie* | | | Title
| Dicarbonyl-, Carbamoyl-carbonyl-und Carbomethoxo-carbonyl-Komplexe des Rhodiums mit tri-und tetratertiären Phosphinliganden [1] Dicarbonyl-, Carbamoyl-carbonyl-and Carbomethoxo-carbonyl Complexes of Rhodium with Tri-and Tetratertiary Phosphine Ligands [1]  | | | | Abstract
| The cationic dicarbonyl complexes [Rh(CO)2(R2PCH2)3CR']PF6 (R = C6H5; R' = CH3, -CH2PR2), formed by high pressure synthesis from RhCl3(H20)3, CO and (R2PCH2)3CR' react with liquid ammonia at 20 °C to give the carbamoyl complexes Rh(CO)(CONH2)(R2PCH2)3CR'. At 100 °C in liquid ammonia the carbamoyl-carbonyl complexes Rh(CO)(CONH2)(R2PCH2)3CR' form the CO-bridged, dinuclear compounds (^-CO)2[Rh(R2PCH2)3CR']2. Upon treatment of Rh(CO)(CONH2)(R2PCH2)3CR' with CH3OH the carbomethoxo carbonyl complexes Rh(CO)(COOCH3)(R2PCH2)3CR' are obtained. The new compounds were characterised, as far as possible, by their IR, Raman and 31 P NMR spectra. | | | |
Reference
| Z. Naturforsch. 35b, 661—668 (1980); eingegangen am 10. Dezember 1979/30. Januar 1980 | | | |
Published
| 1980 | | | |
Keywords
| Rhodium Complexes, Polytertiary Phosphines, IR Spectra, Raman Spectra, 31 P NMR Spectra | | | |
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| default:Reihe_B/35/ZNB-1980-35b-0661.pdf | | | | Identifier
| ZNB-1980-35b-0661 | | | | Volume
| 35 | |
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