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'Polysilanes' in keywords Facet   Publication Year 1996  [X]
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1Author    Wolfram Uhlig, HerrnRequires cookie*
 Title    Zur Darstellung neuer Polysiline und vernetzter Polysilane Synthesis of Novel Polysilynes and Branched Polysilanes  
 Abstract    The reductive coupling of halogenated oligosilanes with potassium-graphite leads to novel polysilynes and branched polysilanes. The ratio of quarternary silicon atoms, monoorganosilyl-and diorganosilylgroups in the polymers can be modified by variation in the structure of the starting materials. In this way the properties of the preceramic polymers (molecular weights, solubility, content of carbon, degree of cross-linking) are influenced. The compounds are characterized by 29Si NMR spectroscopy. 
  Reference    Z. Naturforsch. 51b, 703—710 (1996); eingegangen am 18. Dezember 1995 
  Published    1996 
  Keywords    Polysilanes, Polysilynes, Silyltriflates, Potassium-graphite 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0703.pdf 
 Identifier    ZNB-1996-51b-0703 
 Volume    51