| | 1 | Author
| Jörg Adel, Frank Weller, Kurt Dehnicke | Requires cookie* | | | Title
| Synthese und Kristallstrukturen der spirocyclischen Polyselenido-Komplexe [Na-15-Krone-5] 2 [M(Se 4 ) 2 ] mit M = Zink, Cadmium und Quecksilber Sythesis and Crystal Structures of the Spirocyclic Polyselenido Complexes [Na-15-Crown-5] 2 [M(Se 4 ) 2 ] with M = Zink, Cadmium, and Mercury  | | | | Abstract
| The title compounds have been prepared by reactions of the metal acetates of zink, cadmium, and mercury with ethanolic solutions of sodium polyselenides in the presence of 15-crown-5. They form dark red crystals, which were characterized by their IR specta as well as by X-ray crystal structure determinations. All complexes [Na-15-crown-5] 2 [M(Se 4) 2 ] with M = Zn (1), Cd (2), Hg (3) crystallize isotypically in the space group C2/c with 4 formula units per unit cell. In the anions [M(Se 4) 2 ] 2 ^ the metal atoms are coordinated tetrahedrally by four selenium atoms of two Se 4 2 ~ units, thus forming a spiro-bicyclus. The complex cations [Na-15-crown-5] + have a Na---Se contact of approximately 299 pm with two selenium atoms of a MSe 4 group, allowing formulation of triple ion species. | | | |
Reference
| Z. Naturforsch. 43b, 1094—1100 (1988); eingegangen am 4. Mai 1988 | | | |
Published
| 1988 | | | |
Keywords
| Polyselenide Complexes of Zink, Cadmium, Mercury, Syntheses, Crystal Structure | | | |
Similar Items
| Find | | | DEBUG INFO
| | | | | TEI-XML for
| default:Reihe_B/43/ZNB-1988-43b-1094.pdf | | | | Identifier
| ZNB-1988-43b-1094 | | | | Volume
| 43 | |
|
