| | 1 | Author
| Wieland Krüger, Michael Sell, Reinhard Schmutzler | Requires cookie* | | | Title
| A New Synthesis of Organodifluorophosphites and their Reactions with Platinum(II) Complexes  | | | | Abstract
| Alkyldifluorophosphites, ROPF2 (R = ^-substituted benzyl group, neopentyl, 1-ada-mantyl) have been obtained by a new method, involving reaction of the appropriate alkyl trimethylsilylether, ROSiMe3 with chlorodifluorophosphine, PF2C1. Reactions of these difluorophosphites with platinum(II) complexes of the type [LaPtCla] (L = PEt3, PPI13) led to products such as irans-[L2PtCl(POF2)] and {[p-XC6H4CH2PPh3]+}2[Pt(POF2)4] 2 -, (X = H, Me, Cl, N02). The ease of carbon-oxygen cleavage in ROPF2 is characteristically related to the nature of the leaving group, R. | | | |
Reference
| Z. Naturforsch. 38b, 1074—1080 (1983); received April 25 1983 | | | |
Published
| 1983 | | | |
Keywords
| Organodifluorophosphites, Difluorophosphonate Complexes, Platinum, NMR Spectra | | | |
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| default:Reihe_B/38/ZNB-1983-38b-1074.pdf | | | | Identifier
| ZNB-1983-38b-1074 | | | | Volume
| 38 | |
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