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'Platinum' in keywords Facet   section ZfN Section B:Volume 038  [X]
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1983 (1)
1Author    Wieland Krüger, Michael Sell, Reinhard SchmutzlerRequires cookie*
 Title    A New Synthesis of Organodifluorophosphites and their Reactions with Platinum(II) Complexes  
 Abstract    Alkyldifluorophosphites, ROPF2 (R = ^-substituted benzyl group, neopentyl, 1-ada-mantyl) have been obtained by a new method, involving reaction of the appropriate alkyl trimethylsilylether, ROSiMe3 with chlorodifluorophosphine, PF2C1. Reactions of these difluorophosphites with platinum(II) complexes of the type [LaPtCla] (L = PEt3, PPI13) led to products such as irans-[L2PtCl(POF2)] and {[p-XC6H4CH2PPh3]+}2[Pt(POF2)4] 2 -, (X = H, Me, Cl, N02). The ease of carbon-oxygen cleavage in ROPF2 is characteristically related to the nature of the leaving group, R. 
  Reference    Z. Naturforsch. 38b, 1074—1080 (1983); received April 25 1983 
  Published    1983 
  Keywords    Organodifluorophosphites, Difluorophosphonate Complexes, Platinum, NMR Spectra 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-1074.pdf 
 Identifier    ZNB-1983-38b-1074 
 Volume    38