| 1 | Author | K. D. Buse, H. J. Keller, D. Nöthe | Requires cookie* |
| Title | Pt(NH3)2(SCN)2J: Ein Platinkomplex mit gemischter Wertigkeit Pt(NH3)2(SCN)2I: A Mixed Valence Platinum Compound  | ||
| Abstract | Pt(NH3)2(SCN)2 dissolved in liquid SO2 reacts with molecular iodine to yield a green lustrous solid of stoichiometry Pt(NH3)2(SCN)2I. The compound is diamagnetic in the solid state and in solution and has to be taken for a platinum(II, IV) mixed valence compound, therefore. Chemical and physical evidence so far suggest a linear chain solid with either iodide-bridged metal complex chains or metal complex stacks with parallel triiodide chains. | ||
| Reference | (Z. Naturforsch. 31b, 194—197 [1976]; eingegangen am 13. Oktober 1975) | ||
| Published | 1976 | ||
| Keywords | Metal Complexes, Mixed Valence, Linear Chain Complexes, Platinum | ||
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