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1980[X]
1Author    Sibbele Hietkamp, Reinhard SchmutzlerRequires cookie*
 Title    Eine neue Synthese von Fluorphosphonat-Komplexen des Palladiums und Platins A New Synthesis of Fluorophosphonato Complexes of Palladium and Platinum  
 Abstract    Addition of phosphorus(III) ligands, L (L = tertiary phosphine, phosphite) to the reaction mixture of allyldifluorophosphite (1) with (C 6 H5CN)2MCl2 (2) (M = Pd, Pt) was found to produce two types of products: after a shorter reaction period, monofluoro-phosphonate complexes of the previously known type £rans-L2MCl(POF2) (6) are obtained while over prolonged periods of time bis-fluorophosphonato complexes, Zrans-L2M(POF2)2 (7) are formed. By contrast, Bu"OPF2 (8) yields a mixture of «rans-L2PtCl(POF2) (6) and <rons-L2PtCl[(Bu"0)(F)P0] (10) (L = Ph3P), the latter originating from (Bu re O)2PF formed by ligand scrambling in Bu*OPF2; no products containing more than one fluorophos-phonate group are formed in this case. The new monofluorophosphite, (CH2 = CHCH20)2PF (10) was found to react rapidly with (C6H5CN)2PtCl2/L with formation of L2PtCl[(CH2==CHCH20)(F)P0] (11). Compound characterization was by IR, 19 F and 31 P NMR spectroscopy. 
  Reference    Z. Naturforsch. 35b, 548—553 (1980); eingegangen am 2. November 1979 
  Published    1980 
  Keywords    Palladium, Platinum, Fluorophosphonato Complexes 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0548.pdf 
 Identifier    ZNB-1980-35b-0548 
 Volume    35