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1991 (1)
1Author    R. Benn, P. Betz, R. G. Oddard, P. W. Jolly, N. Kokel, C. Krüger, I. TopalovićRequires cookie*
 Title    Intermediates in the Palladium-Catalyzed Reaction of 1,3-Dienes, Part 6 [1] A Solid-State NM R Spectroscopic Investigation of Butadiene Complexes of Nickel, Palladium and Platinum  
 Abstract    The structure of the (l,3-butadiene)M (R2PC 2H 4P R 2) com pounds (M = Ni, Pd, Pt; R = Pr', Bu', Cy) in the solid-state have been investigated by 13C and 31P CP/MAS N M R spectroscopy. The bonding mode adopted by the diene is dependent upon the nature o f the metal: the palla­ dium com pounds contain an ^2-diene molecule, the nickel compound where R is cyclohexyl contains an ^4-diene molecule whereas the PKPC2H4PPH-stabilized platinum compound con­ tains a platinacyclopentene ring. The crystal structures of (//2-l,3-C4H6)Pd(Cy2PC2H4PCy2) and (/74-l,3-C4H 6)Ni(Cy2PC2H 4PCy2) have been confirmed by X-ray diffraction. 
  Reference    Z. Naturforsch. 46b, 1395—1405 (1991); received M arch 28 1991 
  Published    1991 
  Keywords    Palladium-Organo Complex, Nickel-Organo Complex, Platinum-Organo Complex, Butadiene Complex, X-Ray 
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 TEI-XML for    default:Reihe_B/46/ZNB-1991-46b-1395.pdf 
 Identifier    ZNB-1991-46b-1395 
 Volume    46