| | 1 | Author
| Oligophosphine Ligands, Xxxiv, Lutz Dahlenburg | Requires cookie* | | | Title
| Oligophosphan-Liganden, XXXIV** Organoplatin(II)-Komplexe mit (+ )-(l *S)-l,2-Bis(diphenylphosphino)- 1 -phenylethan-Koordination  | | | | Abstract
| O rganoplatinum (II) Complexes with (+)-(1 5)-1,2-Bis(diphenylphosphino)-1-phenylethane Coordination A ndrea Saare Reaction o f (C8H 12)P t(C H 2C M e3)2 with (+)-(l S)-Ph2P CH (Ph)C H 2P Ph2, S-PHEPHO S, gave (5'-PH EPH O S)Pt(C H2C M e3)2 (1). Cleavage o f one o f the P t -C bonds o f this com pound with m ethanolic HC1 yielded (5-PH EPH O S)PtC l(CH 2C M e3) (2) which could be converted to (5-PH EPH O S)PtH (C H 2C M e3) (3) by treatment with N a[H B (O M e)3], The com plexes so ob tained were characterized by N M R spectroscopy (preferentially 31P) as well as by an X-ray structure analysis performed on the dineopentyl derivative 1. While thermal generation o f (S'-PHEPHOS)Pt(O) from 3 in the presence o f H C = C C (0)0 C M e 3 produced the alkyne co | | | |
Reference
| Z. Naturforsch. 47b, 247 (1992); eingegangen am 24. Juli 1991 | | | |
Published
| 1992 | | | |
Keywords
| Chiral Bis(phosphine) Ligand, Platinum Complexes, X -Ray, Thermolysis | | | |
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| default:Reihe_B/47/ZNB-1992-47b-0247.pdf | | | | Identifier
| ZNB-1992-47b-0247 | | | | Volume
| 47 | |
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