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'Platinum Complex' in keywords Facet   Publication Year 1992  [X]
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1992[X]
1Author    Oligophosphine Ligands, Xxxiv, Lutz DahlenburgRequires cookie*
 Title    Oligophosphan-Liganden, XXXIV** Organoplatin(II)-Komplexe mit (+ )-(l *S)-l,2-Bis(diphenylphosphino)- 1 -phenylethan-Koordination  
 Abstract    O rganoplatinum (II) Complexes with (+)-(1 5)-1,2-Bis(diphenylphosphino)-1-phenylethane Coordination A ndrea Saare Reaction o f (C8H 12)P t(C H 2C M e3)2 with (+)-(l S)-Ph2P CH (Ph)C H 2P Ph2, S-PHEPHO S, gave (5'-PH EPH O S)Pt(C H2C M e3)2 (1). Cleavage o f one o f the P t -C bonds o f this com pound with m ethanolic HC1 yielded (5-PH EPH O S)PtC l(CH 2C M e3) (2) which could be converted to (5-PH EPH O S)PtH (C H 2C M e3) (3) by treatment with N a[H B (O M e)3], The com plexes so ob­ tained were characterized by N M R spectroscopy (preferentially 31P) as well as by an X-ray structure analysis performed on the dineopentyl derivative 1. While thermal generation o f (S'-PHEPHOS)Pt(O) from 3 in the presence o f H C = C C (0)0 C M e 3 produced the alkyne co­ 
  Reference    Z. Naturforsch. 47b, 247 (1992); eingegangen am 24. Juli 1991 
  Published    1992 
  Keywords    Chiral Bis(phosphine) Ligand, Platinum Complexes, X -Ray, Thermolysis 
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 TEI-XML for    default:Reihe_B/47/ZNB-1992-47b-0247.pdf 
 Identifier    ZNB-1992-47b-0247 
 Volume    47