| | 1 | Author
| Z. Naturforsch | Requires cookie* | | | Title
| Darstellung, Eigenschaften und elektronische Raman-Spektren von Di(bromo)phthalocyaninatometallaten(III) der Eisengruppe  | | | | Abstract
| Synthesis, P ro p erties an d E lectronic R am an Spectra of D i(b ro m o)p h th alo cy an in ato m etalates(III) of the Iron G roup E lem ents Svend Sievertsen, H en d rik Schlehahn, H ein er H om borg Low spin di(bromo)phthalocyaninatometalates of tervalent iron, ruthenium and osmium ([MBr2Pc2-]') are formed by the reaction of [FeBrPc2~] or H[MBr2Pc2 ] (M = Ru, Os) with ex cess bromide in DMF or THF and isolated as ("Bu4N)+ salts. The electronic spectra show the typical J i-jr*-transitions (B, Q, N region) of the Pc2~ ligand together with a number of extra bands due to trip-multiplett and (Pc, Br — » M)CT transitions. vs(MBr) is observed in the resonance Raman (RR) spectrum (RR enhanced for M = Fe, Ru) at 161 cm-1 (Fe), 183 cm4 (Ru) and 192 cm-1 (Os), vas(MBr) at 251 cm4 (Fe), 234 cm-1 (Ru) and 218 cm-1 (Os) in the FIR spectra. The RR spectra obtained by excitation at low absorbance between the B and Q region are dominated by the intraconfigurational 'T 7 — > r 8" transition due to spin orbit split ting of the 2T2g ground state for Fe at 583 cm-1, Ru at 1026/1050 cm-1 and Os at 3131 cm4 . In the MIR resp. NIR spectra vibronically induced transitions are observed for the Ru or Os complex. | | | |
Reference
| (Z. Naturforsch. 49b, 50—56 [1994]; eingegangen am 31. August 1993) | | | |
Published
| 1994 | | | |
Keywords
| Phthalocyanines, Electronic Spectra, Vibrational Spectra, Electronic Resonance Raman Spectra | | | |
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| default:Reihe_B/49/ZNB-1994-49b-0050.pdf | | | | Identifier
| ZNB-1994-49b-0050 | | | | Volume
| 49 | |
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