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'Phthalocyanine' in keywords Facet   section ZfN Section B  [X]
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1Author    Konrad Mitulla, Michael HanackRequires cookie*
 Title    Poly-trans(alkinyl)phthalocyaninatosihcium(rV) Synthesis and Properties of a New Kind of One-Dimensional Conductors Poly-trans (alkyny 1)phthalocyaninatosilicon (IV)  
 Abstract    Dichloro(phthalocyaninato)silicon(IV) (1) reacts with various bis-bromomagnesium-alkynes to form the corresponding poly-trans(a]kynyl)phthalocyaninatosilicon(IV) com-pounds (5), (11) and (13). The electrical conductivity of 5, 11 and 13 was measured with and without doping. 
  Reference    Z. Naturforsch. 35b, 1111—1114 (1980); eingegangen am 9. Mai 1980 
  Published    1980 
  Keywords    Organic Conductors, Phthalocyanines, Conducting Polymers 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-1111.pdf 
 Identifier    ZNB-1980-35b-1111 
 Volume    35 
2Author    Josef Metz, Georg Pawlowski, Michael HanackRequires cookie*
 Title    Lösliche Phthalocyaninatometalloxane, Dotierung und Leitfähigkeit Soluble Phthalocyaninatometaloxanes, Doping and Conductivity  
 Abstract    The polymeric //-oxo-(tetraalkylphthalocyaninato)-metal IVB derivatives la-d were synthesized by thermal condensation of the monomeric dihydroxo(tetraalkylphthalo-cyaninato)-metal IVB compounds 5 a-d. The high solubility of the metaloxanes la-d enables a homogeneous reaction with the dopant. The electrical conductivities of the undoped and doped compounds are reported. 
  Reference    Z. Naturforsch. 38b, 378—382 (1983); eingegangen am 9. November 1982 
  Published    1983 
  Keywords    Phthalocyanine, Doping, Conductivity, Polymer 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0378.pdf 
 Identifier    ZNB-1983-38b-0378 
 Volume    38 
3Author    D. Ieter Wöhrle, UweH. Ündorf, G. Ünter, Schulz-Ekloff, Erwin IgnatzekRequires cookie*
 Title    Phthalocyanines on Mineral Carriers, 2* Synthesis of Cobalt(II) and Copper(II)-phthalocyanines on y-Al20 3 and S i0 2  
 Abstract    The reaction o f metal loaded y -A l20 3 and S i 0 2 with benzene-1,2-dicarbonitrile (2) resp. 1H-isoind ole-l,3(H)diim ine (3) results in the /^-modification o f m etallized phthalocyanines (1; metals: C u(II), C o(II)). 1 is form ed with an average yield o f 4 8 —64% in uniform distribution on the carriers from the reaction with 2. The sizes o f the surface areas of the supports are not changed significantly by loading with 1. Non-uniform distribution or even unsupported crystals o f 1 are found if the synthesis is carried out with 3. 
  Reference    Z. Naturforsch. 41b, 179 (1986); received A ugust 19 1985 
  Published    1986 
  Keywords    Phthalocyanines, Mineral Carriers, A lum ina, Silica 
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 TEI-XML for    default:Reihe_B/41/ZNB-1986-41b-0179.pdf 
 Identifier    ZNB-1986-41b-0179 
 Volume    41 
4Author    Z. NaturforschRequires cookie*
 Title    Darstellung, Eigenschaften und elektronische Raman-Spektren von Di(bromo)phthalocyaninatometallaten(III) der Eisengruppe  
 Abstract    Synthesis, P ro p erties an d E lectronic R am an Spectra of D i(b ro m o)p h th alo cy an in ato m etalates(III) of the Iron G roup E lem ents Svend Sievertsen, H en d rik Schlehahn, H ein er H om borg Low spin di(bromo)phthalocyaninatometalates of tervalent iron, ruthenium and osmium ([MBr2Pc2-]') are formed by the reaction of [FeBrPc2~] or H[MBr2Pc2 ] (M = Ru, Os) with ex­ cess bromide in DMF or THF and isolated as ("Bu4N)+ salts. The electronic spectra show the typical J i-jr*-transitions (B, Q, N region) of the Pc2~ ligand together with a number of extra bands due to trip-multiplett and (Pc, Br — » M)CT transitions. vs(MBr) is observed in the resonance Raman (RR) spectrum (RR enhanced for M = Fe, Ru) at 161 cm-1 (Fe), 183 cm4 (Ru) and 192 cm-1 (Os), vas(MBr) at 251 cm4 (Fe), 234 cm-1 (Ru) and 218 cm-1 (Os) in the FIR spectra. The RR spectra obtained by excitation at low absorbance between the B and Q region are dominated by the intraconfigurational 'T 7 — > r 8" transition due to spin orbit split­ ting of the 2T2g ground state for Fe at 583 cm-1, Ru at 1026/1050 cm-1 and Os at 3131 cm4 . In the MIR resp. NIR spectra vibronically induced transitions are observed for the Ru or Os complex. 
  Reference    (Z. Naturforsch. 49b, 50—56 [1994]; eingegangen am 31. August 1993) 
  Published    1994 
  Keywords    Phthalocyanines, Electronic Spectra, Vibrational Spectra, Electronic Resonance Raman Spectra 
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 TEI-XML for    default:Reihe_B/49/ZNB-1994-49b-0050.pdf 
 Identifier    ZNB-1994-49b-0050 
 Volume    49 
5Author    Heinrich Homborg, Winfried KalzRequires cookie*
 Title    Darstellung von Phthalocyaninen von Ib-Elementen in aprotischen Lösungsmitteln Preparation of Phthalocyanines of lb-Elements in Aprotic Solvents  
 Abstract    The double decomposition of (TDBA)LiPc(2-) with halocomplexes of the lb-elements is investigated in nonpolar aprotic solvents. Phthalocyanines of the formula MLiPc(2-) are isolated only for the univalent cations Cu(I) and Ag(I), but not for Au(I). The impure AgLiPc(2-) is light sensitive. In contrast to earlier observations only oxidation products of the phthalocyanine anion are obtained in the presence of Cu(II) and Au(III). The preparation of Ag(II) and Au(II) phthalocyanines failed. Abkürzungen: TBA+ = w-Tetrabutylammonium, [(C4H9)4N]+, TDBA+ = n-(Tridodecyl-butyl)ammonium, [(Cl2H25)3C4H9N]+, Pc(2-) = Phthalocyanin(2-), [C32HI6N8] 2 -, Pc(l-) = Phthalocyanin(l-), 
  Reference    Z. Naturforsch. 33b, 1063—1066 (1978); eingegangen am 29. Juni/31. Juli 1978 
  Published    1978 
  Keywords    Phthalocyanine, Copper(I), Silver(I), UV-VIS, Vibrational Spectra 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-1063.pdf 
 Identifier    ZNB-1978-33b-1063 
 Volume    33