| | 1 | Author
| Heinz-Peter Schuchmann, Heinz Bandmann, Clemens Von Sonntag | Requires cookie* | | | Title
| The 185 nm Photolysis of 1,4-Dioxane in the Liquid Phase  | | | | Abstract
| The main products in the 185 nm photolysis of neat 1,4-dioxane are formaldehyde (0 = 0.25), glycol monovinyl ether (0.17), and ethylene (0.15). Some hydrogen (0.04), carbon monoxide (0.01), acetaldehyde (0.03), oxetane (0.04), and bidioxanyl (0.01) are also formed. On N20-saturation, the quantum yields of these products are diminished by about 30%, and N2 (0.59) and hydroxydioxane (0.4) become the main products. They are thought to be formed in the reaction sequence hv dioxane > • dioxane* dioxane* + N20 > • dioxane + N2 + O O + dioxane > • hydroxydioxane In aqueous dioxane, photoionisation is possible due to a greater lowering of the ionisa-tion threshold. In dioxane/water 20:80 the main products are H2 (0.50) and bidioxanyl (0.45), most likely formed in consequence of (dioxane)aq (dioxane)aq + eäq (dioxane)Jq • (dioxane-H)-+ H+ eäq + H+ > H-H-+ dioxane >-H2 + (dioxane-H)-2 (dioxane-H)- • bidioxanyl | | | |
Reference
| Z. Naturforsch. 34b, 327—332 (1979); received October 6 1978 | | | |
Published
| 1979 | | | |
Keywords
| Photolysis, 1, 4-Dioxane, Photoionisation, Energy Transfer, Quantum Yields | | | |
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| default:Reihe_B/34/ZNB-1979-34b-0327.pdf | | | | Identifier
| ZNB-1979-34b-0327 | | | | Volume
| 34 | |
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