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1Author    H. Parlar, R. Baumann, M. BahadirRequires cookie*
 Title    Triplett-sensibilisierte Isomerisierung des Insektizids Thiodan Triplet Sensibilized Isomers of the Insecticide Thiodane  
 Abstract    The photoisomerization reactions of cyclodiene insecticide Thiodane were investigated in dif-ferent solvent systems, with wavelengths above 290 nm. The results show that /S-isomere (2) can be converted in the presence of acetone into the a-isomere (1). Photokinetic experiments give sufficient information on the character of the excited state of these compounds. 
  Reference    Z. Naturforsch. 37b, 260—263 (1982); eingegangen am 26. Oktober 1981 
  Published    1982 
  Keywords    Thiodane, Photochemical Reactions, Isomerization 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-0260_n.pdf 
 Identifier    ZNB-1982-37b-0260_n 
 Volume    37 
2Author    Richard Korswagen, ManfredL. ZieglerRequires cookie*
 Title    Darstellung von "Nitrenkomplexen" via Säureazide und Azidosäureester Synthesis of "Nitrene Complexes" via Acid Azides and Azido Acid Esters  
 Abstract    The photochemical reaction of carboxylic acid azides and azido carboxylic acid esters, respectively, with ^ 5 -C5H5Mo(CO)3CH3 in CH2CI2 seems to be a general route to the nitrene bridged complexes ^ 5 -C5H5(0 =)M0-iu(0)-(u(NC0R)M0(= 0)-r? 5 -C5H5 and ^-C5H5(0 -)Mo-/I(0)-/*(NC00R)Mo(-OJ-TJÖ-CSHS. 
  Reference    Z. Naturforsch. 35b, 1196—1200 (1980); eingegangen am 30. Juni 1980 
  Published    1980 
  Keywords    Nitrene Complexes, Photochemical Reaction, Acid Azides 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-1196.pdf 
 Identifier    ZNB-1980-35b-1196 
 Volume    35 
3Author    CorneliusG. Kreiter, Klaus LehrRequires cookie*
 Title    Photochemische Reaktionen von Übergangsmetall-Organyl-Komplexen mit Olefinen, VI [1] Reaktionen von Tricarbonyl-T]5-2,4-cyclohexadienyl-mangan mit konjugierten Dienen Photochem ical Reactions of Transition Metal Organyl Complexes with Olefins, VI [1] Reactions o f Tricarbonyl (^5-2,4-cyclohexadienyl)manganese with Conjugated Dienes  
 Abstract    Tricarbonyl-?/5-2,4-cyclohexadien-l-yl-manganese (1) was reacted photochemically at 253 K with simple conjugated dienes. Four different types of products were obtained, depending upon the dienes. With 1,3-butadiene (A) dicarbonyl-743-l-(3-buten-l,2-diyl)-2,4-cyclohexa-diene-manganese (2 A) is isolated. 2-Methyl-1,3-butadiene (B) yields the methyl-substituted diastereomeric dicarbonyls 2B, 2B', the [4+5]-cycloadduct tricarbonyl-//3:2-3-methyl-bicyclo-[4.3. l]-3,8-decadien-7-yl-manganese (3B) and tetracarbonyl-?/3-4-methylene-bicyclo[4.3. l]-8-decen-3-yl-manganese (4B) with an exocyclically coordinated tetracarbonylm anganese frag­ ment. W ith 2,3-dimethyl-1,3-butadiene (C) only the [4+5]-cycloadduct 3C and the tetracar-bonyl 4C are obtained. No CC-bond formation is observed with ^,^-2,4-hexadiene (D) and 1,3-cyclohexadiene (E). Carbonyl-75-2,4-cyclohexadien-1 -yl-74-£,> £'-2,4-hexadiene-manganese (5D), and carbonyl-74-l,3-cyclohexadiene-^5-2,4-cyclohexadien-l-yl-manganese (5E) are the only products. The complexes were separated and purified by HPL chrom atography. Their constitutions were determined by IR and N M R spectroscopy. 
  Reference    Z. Naturforsch. 46b, 1377—1383 (1991); eingegangen am 4. April 1991 
  Published    1991 
  Keywords    Diene Controlled C -C Bond Form ation, Manganese, Photochemical Reactions 
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 TEI-XML for    default:Reihe_B/46/ZNB-1991-46b-1377.pdf 
 Identifier    ZNB-1991-46b-1377 
 Volume    46 
4Author    William Clegg, Uwe Klingebiel, GeorgeM. SheldrickRequires cookie*
 Title    Attack by a Lithiated Aminofluorosilane on the C-0 Bond of Cr(CO)6; Formation of Isonitrile Complexes  
 Abstract    The photochemical reaction of a lithiated aminofluorosilane with Cr(CO)6 leads to sub-stitution of one or two carbonyl oxygen atoms and formation of isonitrile complexes. The crystal structure of the disubstituted product, cis-di(<er£-butyhsonitrile)tetracarbonylchromium, has been determined. 
  Reference    Z. Naturforsch. 38b, 260—261 (1983); eingegangen am 6. Oktober 1982 
  Published    1983 
  Keywords    Lithium -aminofluorosilane, Chromium Carbonyl, Photochemical Reaction, Crystal Structure, Isonitrile Complex 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0260_n.pdf 
 Identifier    ZNB-1983-38b-0260_n 
 Volume    38