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'Photobiology' in keywords Facet   Publication Year 1975  [X]
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1975[X]
1Author    N. Puppala, S. S. BrodyRequires cookie*
 Title    Interactions between Retinal and Phospholipids in Monomolecular Films at Acid pH  
 Abstract    The surface properties of mixed monomolecular films of retinal and phospholipids (p. lipids) are measured as a function of mole fraction at a nitrogen-water interface. An acid pH of 6.0 is maintained in the aqueous phase. Before irradiation the surface potential A V for 9-cis retinal, 11-cis retinal, phosphatidyl serine (PS) and phosphatidyl ethanolamine (PE), at j t = 12 dyn/cm, are 490 mV, 645 mV, 548 mV and 375 mV, respectively. Before irradiation, A 0 for 9-cis and 11-ds are 58 Ä2 and 48 A2, respectively. Experimentally measured isotherms are compared with theo­ retically calculated isotherms. In case of mixed films of retinal and PS the experimental isotherms are greater than theoretical, while mixed films of retinal and PE are smaller than theoretical. A maximum value for the difference between theoretical and experimental areas are obtained at (retinal) / (p. lipid) = 0 .1 . Retinal and p. lipid do not appear to form a Schiff base, charge transfer or any other type of complex at pH 6. A eutectic type mixture between retinal and p. lipid may occur on the surface. A light induced change in A V of —130 mV is observed in the case of 11-cis and PE. The significance of these findings with respect to visual excitation is considered. 
  Reference    (Z. Naturforsch. 30c, 478—483 [1975]; received October 4 1973/October 21 1974) 
  Published    1975 
  Keywords    ) Vision, Retinal, Monolayers, Photobiology, Membranes 
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 TEI-XML for    default:Reihe_C/30/ZNC-1975-30c-0478.pdf 
 Identifier    ZNC-1975-30c-0478 
 Volume    30