1 | Author | Tjark Siedentop, Ion Neda, Reinhard Schmutzler | Requires cookie* |
Title | Synthese und Komplexierung phosphorylierter spacer-modifizierter Glucosederivate Synthesis and Complexation of Spacer Modified Phosphorylated Glucose Derivatives ![]() | ||
Abstract | Treatment of the spacer modified glucose derivative 1 with diethylaminotrimethylsilane furnished the bis-silylated molecule 2. Reaction of 2 with two equivalents of the phosphorus compounds 3, 4, and 5 led to the spacer phosphorylated glucosyl derivatives 6, 7 and 8. Complexation of 6 with (COD)PtCl2 gave complex 9; the ds-conform ation of 9 could be confirmed by 31P NMR investigations. | ||
Reference | Z. Naturforsch. 55b, 956—960 (2000); eingegangen am 20. Juli 2000 | ||
Published | 2000 | ||
Keywords | Glucopyranosides, Phosphorylation, Platinum Complex | ||
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