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'Phosphorylated Alcohols' in keywords
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1980 (1)
1978 (1)
1Author    Ekkehard Lindner, Hans LesieckiRequires cookie*
 Title    Das Verhalten von (Halogen)Acyldiphenylphosphinen gegenüber molekularem Sauerstoff in Abhängigkeit vom Acylrest Behavior of (Halogeno) Acylphosphines Towards Molecular Oxygen in Dependence of the Acyl Residue  
 Abstract    The halogenated acylphosphines RC(0)PPh2 (la-f) [R = C1CH2 (a), FCH2 (b), F2CH (c), C2F5 (d), C3F7 (e), CöFö (f)], which can be oxidized by rigorously dried oxygen to the phos-phine oxides RC(0)P(0)Ph2 (2a-f), are obtained by reaction of NaPPh2 with the acyl chlorides RC(0)C1. From 2a-f and stoichiometric amounts of water the alcohols RC[Ph2P(0)]20H (3a-f) are formed. While 3c-f are isomerized into the phosphinates RC[Ph2P(0)][0P(0)Ph2]H (4c-f), the alcohols 3a, b are stable. The hydrolytic and thermal behavior of the phosphine oxides 2 and the alcohols 3 are discussed regarding the nature of the acyl residue. 
  Reference    Z. Naturforsch. 33b, 849—854 (1978); eingegangen am 13. Juni 1978 
  Published    1978 
  Keywords    Acylphosphines, Acylphosphine Oxides, Phosphorylated Alcohols, IR, 31 P{ 1 H}NMR 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0849.pdf 
 Identifier    ZNB-1978-33b-0849 
 Volume    33 
2Author    Ekkehard Lindner, Gerhard FreyRequires cookie*
 Title    Darstellung und Eigenschaften von (Trifluor)acetylphosphol Preparation and Properties of (Trifluoro)acetylphosphole  
 Abstract    The acylphospholes RC(0)PRR (la,b) [R = CH3 (a), CF3 (b); PRR = which are available from dibenzophosphole and the anhydrides [RC(0)]20 react in ether with 
  Reference    Z. Naturforsch. 35b, 1150—1154 (1980); eingegangen am 24. März 1980 
  Published    1980 
  Keywords    (Trifluoro)acetylphospholes, Phosphole Oxides, Phosphorylated Alcohols, III Spectra, NMR Spectra 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-1150.pdf 
 Identifier    ZNB-1980-35b-1150 
 Volume    35